125750-30-3Relevant academic research and scientific papers
(R)(R')P->/-Co(CO)3, ein neutraler Phosphenium-Ion-Komplex mit Phosphor-Cobalt-Mehrfachbindung
Lang, Heinrich,Orama, Olli
, p. C48 - C50 (1989)
The reaction of (2,6-tBu2-4-MeC6H2O)P(Cl)(CCPh) with Co2(CO)8 yields the neutral phosphenium ion complex (R)(R')P->/-Co(CO)3 (R=2,6-tBu2-4-MeC6H2O; R'=(η2-CCPh)Co2(CO)6), a compound with a phosphorus cobalt double bond.
Synthese und Reaktivitaet von Phenylethinyl-substituierten Phosphenium-Ion-Komplexen (R)(R')P=MoCp'(CO)2; Darstellung von Clusterverbindungen, die einen 1-Cobalta-2-Phospha-Heteroallyl Synthesebaustein enthalten
Lang, Heinrich,Leise, Michael,Zsolnai, Laszlo
, p. 349 - 363 (2007/10/02)
The synthesis of the phenylethinyl-chlorophosphines (R)(Cl)P(CC-Ph) (R = 2,6-tBu2-4-MeC6H2O: IVa; R = 2,4,6-tBu3C6H2O: IVb) is described.IV reacts with Cp'(CO)3Mo-, VII, (Cp' = η5-C5H5, ν5-C5Me5) t
