(R)(R')P->/-Co(CO)3, ein neutraler Phosphenium-Ion-Komplex mit Phosphor-Cobalt-Mehrfachbindung

Article abstract of DOI:10.1016/0022-328X(89)85240-4

The reaction of (2,6-^tBu2-4-MeC6H2O)P(Cl)(CCPh) with Co2(CO)8 yields the neutral phosphenium ion complex (R)(R')P->/-Co(CO)3 (R=2,6-^tBu2-4-MeC6H2O; R'=(η²-CCPh)Co2(CO)6), a compound with a phosphorus cobalt double bond.