125782-68-5

Basic information

• Product Name: (S)-1-Benzyloxy-3-(5-hydroxymethyl-furan-2-yl)-propan-2-ol
• CAS NO: 125782-68-5
• Molecular Weight: 262.306
• Mol File: 125782-68-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (S)-1-Benzyloxy-3-(5-hydroxymethyl-furan-2-yl)-propan-2-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-1-Benzyloxy-3-(5-hydroxymethyl-furan-2-yl)-propan-2-ol(125782-68-5)
• EPA Substance Registry System: (S)-1-Benzyloxy-3-(5-hydroxymethyl-furan-2-yl)-propan-2-ol(125782-68-5)

Safety Data

• Hazardous Substances Data: 125782-68-5(Hazardous Substances Data)

Upstream product

• 98-00-0 (2-furyl)methyl alcohol 
• 2930-05-4 (S)-benzyl glycidyl ether 

Downstream Products

• 125801-26-5 (4R,6S,11S)-4-Benzyloxymethyl-2,2-dimethyl-11-vinyl-1,3,7-trioxa-spiro[5.5]undecan-9-one 
• 125782-72-1 (4R,6S,9R,11S)-4-Benzyloxymethyl-9-iodo-2,2-dimethyl-11-vinyl-1,3,7-trioxa-spiro[5.5]undecane 
• 125782-70-9 (4R,6S,11R)-4-Benzyloxymethyl-11-methyl-1,3,7-trioxa-spiro[5.5]undecan-9-one 
• 125782-74-3 (2R,5S)-1-Benzyloxy-2-hydroxy-5-vinyl-oct-7-en-4-one 
• 125782-71-0 (4R,6S,9R,11R)-4-Benzyloxymethyl-9-iodo-11-methyl-1,3,7-trioxa-spiro[5.5]undecane 
• 125782-73-2 (2R,5R)-1-Benzyloxy-2-hydroxy-5-methyl-oct-7-en-4-one 
• 125643-07-4 (4S,6R)-4-Benzyloxymethyl-2,2-dimethyl-1,3,7-trioxa-spiro[5.5]undec-10-en-9-one 

Relevant articles and documents

Methodology for the Enantioselective Synthesis of Aldols and Other 1,3-Dioxygenated Systems

The enantioselective synthesis of the spiroenones 3, 4 from (S)-glycidol-O-benzyl ether and lithiated furan derivatives is described.After conjugate addition of lithium dimethyl cuprate or lithium divinyl cuprate and conversion of the resulting saturated ketones to their respective iodides 7 and 8, fragmentation of these halides leads to the formation of acyclic aldol-containing carbon skeletons.