125975-36-2

Basic information

• Product Name: Methanesulfonic acid (R)-4-benzyloxy-2-hydroxy-butyl ester
• Synonyms: Methanesulfonic acid (R)-4-benzyloxy-2-hydroxy-butyl ester
• CAS NO: 125975-36-2
• Molecular Weight: 274.338
• Mol File: 125975-36-2.mol

Chemical Properties

• CAS DataBase Reference: Methanesulfonic acid (R)-4-benzyloxy-2-hydroxy-butyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Methanesulfonic acid (R)-4-benzyloxy-2-hydroxy-butyl ester(125975-36-2)
• EPA Substance Registry System: Methanesulfonic acid (R)-4-benzyloxy-2-hydroxy-butyl ester(125975-36-2)

Safety Data

• Hazardous Substances Data: 125975-36-2(Hazardous Substances Data)

Upstream product

• 100-39-0 benzyl bromide 
• 71998-69-1 (S)-4-benzyloxy-1,2-butanediol 
• 124-63-0 methanesulfonyl chloride 
• 100-44-7 benzyl chloride 
• 5470-84-8 4-benzyloxybutanal 
• 4541-14-4 4-benzyloxy-butan-1-ol 
• 69985-32-6 (R)-4-phenylmethoxy-1,2-butanediol 

Downstream Products

• 91285-64-2 (+)-(2S,4S)-6-(benzyloxy)-1,2-epoxyhexan-4-ol 
• 91285-63-1 (-)-(4S,6S)-4-[2-(benzyloxy)ethyl]-6-(iodomethyl)-1,3-dioxan-2-one 
• 111322-01-1 (R)-1-benzyloxy-hex-5-en-3-ol 
• 944394-26-7 (+)-(4S,6R)-4-[2-(benzyloxy)ethyl]-2,2,6-trimethyl-1,3-dioxane 
• 944394-24-5 (+)-(2R,4S)-6-(benzyloxy)hexane-2,4-diol 
• 204448-48-6 tert-butyl (R)-1-(benzyloxy)hex-5-en-3-yl carbonate 
• 85960-55-0 (S)-(2-phenylmethoxyethyl)oxirane 
• 115114-87-9 (2R)-2-(2-benzyloxyethyl)oxirane 

Relevant articles and documents

[4-(1, 3, 3-TRIMETHYL-2-OXO-3, 4-DIHYDRO-1H-QUINOXALIN-7-YL) PHENOXY]ETHYLOXY COMPOUND OR SALT THEREOF

The present invention relates to a novel [4-(1,3,3-trimethyl-2-oxo-3,4-dihydro-1H-quinoxalin-7-yl)phenoxy]ethyloxy compound or a salt thereof. The compound or a salt thereof of the present invention has a glucocorticoid receptor agonist activity, and is u

Enantioselective synthesis of tarchonanthuslactone using proline-catalyzed asymmetric α-aminooxylation

A practical enantioselective synthesis of tarchonanthuslactone 1, an important natural product with a polyol unit, is described. The sequence of synthetic reactions involves proline-catalyzed α-aminooxylation and iodine-induced electrophilic cyclization as the chiral inducing steps.

An efficient organocatalytic route to the atorvastatin side-chain

An organocatalytic route to the synthesis of the atorvastatin side-chain, a building block present in the statin family, is described using l-proline-catalyzed α-aminooxylation of an aldehyde. The method also employs an iodine-induced intramolecular electrophilic cyclization of a carbonate to produce the iodocarbonate in a highly diastereoselective manner.

Synthesis of (+)-methyl (R,E)-6-benzyloxy-4-hydroxy-2-hexenoate and its mesylate derivative

Methyl (E)-6-benzyloxy-4-hydroxy-2-hexenoate is prepared in both racemic and enantiopure form through reaction between (2-benzyloxy)ethyloxirane and the dianion of phenylselenoacetic acid followed by esterification with diazomethane, oxidation to the selenoxide and subsequent pyrolysis in 72% overall yield.

L-(S)-ERYTHRULOSE : THE SYNTHESYS OF (R)-1,2,4-BUTANETRIOL AND OF SOME RELATED C4 CHIRONS.

L-(S)-Erythrulose can easily be transformed into (R)-1,2,4-butanetriol and related C4 chiral building blocks.A formal synthesis of (-)-GABOB is presented.Also the formation of 3-methylene-1,2,4-butanetriol derivatives is described.