1263309-86-9Relevant academic research and scientific papers
Stereochemistry, total synthesis, and biological evaluation of the new plant hormone solanacol
Chen, Victor X.,Boyer, Franois-Didier,Rameau, Catherine,Retailleau, Pascal,Vors, Jean-Pierre,Beau, Jean-Marie
, p. 13941 - 13945 (2010)
The first total synthesis of solanacol, a member of the strigolactone family, features ring-closing metathesis, enzymatic kinetic resolution, and atom-transfer radical cyclization. This defines the stereostructure of the natural product. The best hormonal
New synthesis of A-ring aromatic strigolactone analogues and their evaluation as plant hormones in pea (pisum sativum)
Chen, Victor X.,Boyer, Fran?ois-Didier,Rameau, Catherine,Pillot, Jean-Paul,Vors, Jean-Pierre,Beau, Jean-Marie
supporting information, p. 4849 - 4857 (2013/05/22)
A new general access to A-ring aromatic strigolactones, a new class of plant hormones, has been developed. The key transformations include in sequence ring-closing metathesis, enzymatic kinetic resolution and a radical cyclization with atom transfer to install the tricyclic ABC-ring system. The activity as plant hormones for the inhibition of shoot branching in pea of various analogues synthesized by this strategy is reported. Inhibiting shoot branching: A new general access to A-ring aromatic strigolactones (see scheme), a new class of plant hormones, has been developed. The biological activity of various analogues synthesized by this strategy for inhibiting bud outgrowth in pea was evaluated. Copyright
