42373-90-0

Upstream product

• 51788-72-8 allyl (3,4-dimethylphenyl) ether 
• 91-66-7 N,N-diethylaniline 
• 95-65-8 3,4-Dimethylphenol 
• 67-66-3 chloroform 
• 1263309-87-0 3-bromo-5, 6-dimethyl-2-hydroxybenzaldehyde 
• 1263309-86-9 2-allyl-6-bromo-4, 5-dimethylphenol 
• 22802-39-7 2-bromo-4,5-dimethylphenol 
• 148918-17-6 1-bromo-4,5-dimethyl-2-(prop-2-en-1-yloxy)benzene 
• 71-41-0 pentan-1-ol 

Downstream Products

• 1263309-88-1 2-formyl-3,4-dimethylphenyltrifluoromethanesulfonate 
• 1263309-89-2 5,6-dimethyl-2-vinylbenzaldehyde 
• 1263309-85-8 1-(2-vinyl-8, 9-dimethylphenyl)prop-2-en-1-ol 
• 1396809-62-3 C₂₄H₃₂N₂O₄ 
• 5628-59-1 5,6-dimethyl-2-hydroxybenzoic acid 

Relevant academic research and scientific papers

New synthesis of A-ring aromatic strigolactone analogues and their evaluation as plant hormones in pea (pisum sativum)

A new general access to A-ring aromatic strigolactones, a new class of plant hormones, has been developed. The key transformations include in sequence ring-closing metathesis, enzymatic kinetic resolution and a radical cyclization with atom transfer to install the tricyclic ABC-ring system. The activity as plant hormones for the inhibition of shoot branching in pea of various analogues synthesized by this strategy is reported. Inhibiting shoot branching: A new general access to A-ring aromatic strigolactones (see scheme), a new class of plant hormones, has been developed. The biological activity of various analogues synthesized by this strategy for inhibiting bud outgrowth in pea was evaluated. Copyright

Stereochemistry, total synthesis, and biological evaluation of the new plant hormone solanacol

The first total synthesis of solanacol, a member of the strigolactone family, features ring-closing metathesis, enzymatic kinetic resolution, and atom-transfer radical cyclization. This defines the stereostructure of the natural product. The best hormonal