1264669-97-7Relevant academic research and scientific papers
Photochemical activation of a metal-organic framework to reveal functionality
Tanabe, Kristine K.,Allen, Corinne A.,Cohen, Seth M.
, p. 9730 - 9733 (2010)
Seeing the light: Two highly porous metal-organic frameworks (MOFs) were transformed using UV light to produce MOFs with hydroxy and catechol groups through an unusual postsynthetic deprotection reaction (see scheme). Copyright
Photopatterning of fluorescent host-guest carriers through pore activation of metal-organic framework single crystals
Stassen,Boldog,Steuwe,De Vos,Roeffaers,Furukawa,Ameloot
, p. 7222 - 7225 (2017/07/11)
Encoded fluorescent particles are fabricated through the selective uptake of dyes in photopatterned metal-organic framework single crystals. The concept is based on spatially controlled photochemical cleavage of pore-blocking pendant groups. Because of the crystalline and porous nature of the host, this approach enables guest uptake that is tunable and can be triggered though controlled irradiation.
