126569-71-9

Basic information

• Product Name: N,N-Dimethyl-N'-(phenylmethylene)-1,2-ethylenediamine
• Synonyms: N,N-Dimethyl-N'-(phenylmethylene)-1,2-ethylenediamine
• CAS NO: 126569-71-9
• Molecular Weight: 176.261
• Mol File: 126569-71-9.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: N,N-Dimethyl-N'-(phenylmethylene)-1,2-ethylenediamine(CAS DataBase Reference)
• NIST Chemistry Reference: N,N-Dimethyl-N'-(phenylmethylene)-1,2-ethylenediamine(126569-71-9)
• EPA Substance Registry System: N,N-Dimethyl-N'-(phenylmethylene)-1,2-ethylenediamine(126569-71-9)

Safety Data

• Hazardous Substances Data: 126569-71-9(Hazardous Substances Data)

Upstream product

• 103-55-9 N,N-dimethyl-N'-benzyl-1,2-ethanediamine 
• 100-52-7 benzaldehyde 
• 108-00-9 N,N-dimethylethylenediamine 

Downstream Products

• 72221-29-5 3,3-dichloro-1-[2-(dimethylamino)ethyl]-4-phenyl-2-azetidinone, hydrochloride 
• 478020-70-1 [PtCl₂(Me₂NCH₂CH₂NCHC₆H₄)] 
• 151387-06-3 (E)-2-Aza-1-phenyl-1,3-butadiene 

Relevant articles and documents

o-Iodoxybenzoic Acid (IBX) as a Viable Reagent in the Manipulation of Nitrogen- and Sulfur-Containing Substrates: Scope, Generality, and Mechanism of IBX-Mediated Amine Oxidations and Dithiane Deprotections

o-Iodoxybenzoic acid (IBX), a highly versatile hypervalent iodine(V) reagent, was found to efficiently mediate the dehydrogenation of amines in addition to facilitating the oxidative cleavage of dithioacetals and dithioketals. Through the development of relevant IBX-based protocols, a plethora of useful synthetic intermediates, including imines, oximes, ketones, and aromatic N-heterocycles, were found to be readily accessible under notably mild conditions. Further investigation of these transformations led to the elucidation of valuable mechanistic details, resulting in the conclusion that they proceed via ionic rather than single electron transfer (SET) pathways.

Stereocontrolled Synthesis of N-Vinyl-, N-(1'-Propenyl)-, and N-Unsubstituted-β-lactams from 2-Aza-1,3-butadienes via the Staudinger Reaction

2-Aza-1,3-butadienes 2 and 5 were synthesized in good yields and on a large scale.Reaction of 2 and 5 with acid chlorides in the presence of triethylamine (Staudinger reaction) resulted in the high-yielding formation of N-vinyl- and N-(1'-propenyl)-β-lact

NEW PESTICIDES AND INTERMEDIATES. PART VIII. QUATERNARY AMMONIUM SALTS OF AZACYCLIC DERIVATIVES

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