126683-83-8Relevant academic research and scientific papers
CONVERSION OF NITRILES TO THIOAMIDES UNDER THE ACTION OF THE BINARY THIONYLATING SYSTEM PHOSPHORUS DITHIOACID-ALCOHOL
Zabirov, N. G.,Shamsevaleev, F. M.,Cherkasov, R. A.
, p. 56 - 63 (2007/10/02)
Binary systems of phosphorus dithioacid-methanol and phosphorus pentasulfide-methanol are effective hydrosulfonating systems for the conversion of aromatic nitriles to the corresponding primary thioamides.In ternary systems nitrile-phosphorus dithioacid-alcohol from one to four parallel processes can occur.The structure of the phosphorus dithioacids has little effect, whereas the structures of the nitrile and alcohol substantially influence both the rate of the processes and the possible pathway.The reactivity of alcohols in these reactions drops with increasing volume of the hydrocarbon radical.
31P CIDNP IN THE REACTION OF ZINC DIISOPROPYLDITHIOPHOSPHATE WITH METHYL ETHYL KETONE PEROXIDE AND CUMENE HYDROPEROXIDE IN BENZENE
Gainullin, R. M.,Ismaev, I. E.,Il'yasov, A. V.
, p. 2029 - 2032 (2007/10/02)
The free-radical nature of the reactions of a series of dithiophosphate complexes of zinc with peroxides was established by 31P chemically induced dynamic nuclear polarization (CIDNP).The polarization coefficient, the reaction rate constant, and the nucle
