127043-84-9

Upstream product

• 19715-32-3 2-bromo-1,3-di-tert-butylbenzene 
• 19715-31-2 5-amino-2-bromo-1,3-di-tert-butylbenzene 
• 19715-30-1 2,6-di-t-butyl-4-nitrobromobenzene 
• 3975-77-7 1-bromo-2,4,6-tri-tert-butylbenzene 
• 5180-59-6 2,6-di-tert-butyl-4-nitro-aniline 
• 516526-98-0 2-bromo-1,3-bis(1-cyano-1-methylethyl)benzene 
• 516526-99-1 2-bromo-1,3-bis(1-formyl-1-methylethyl)benzene 

Downstream Products

• 127043-85-0 C₂₈H₄₂P₂ 
• 740815-87-6 (dibromomethylene)(2,6-di-t-butylphenyl)phosphine 
• 127043-86-1 (1R,2R)-3,3-Dichloro-1,2-bis-(2,6-di-tert-butyl-phenyl)-diphosphirane 
• 127043-86-1 (1R,2S)-3,3-Dichloro-1,2-bis-(2,6-di-tert-butyl-phenyl)-diphosphirane 
• 127043-87-2 1,3-bis(2,6-di-t-butylphenyl)-1,3-diphosphaallene 

Relevant academic research and scientific papers

The electronic effects of bulky aryl substituents on low coordinated phosphorus atoms in diphosphenes and phosphaalkenes by functionalization at the para position

The electronic effects of bulky aryl substituents on low coordinated phosphorus atom(s) in diphosphenes and phosphaalkenes have been examined by means of functionalization at the para position of the substituents. Bulky bromobenzenes bearing an electron-d

Preparation and properties of phosphaethynes bearing bulky aryl groups with electron-donating substituents at the para position

Phosphaethynes bearing a 2,6-di-tert-butyl-4-(dimethylamino)phenyl, 2,6-di-tert-butyl-4-methoxyphenyl, or 2,6-di-tert-butylphenyl group were prepared. A 31P NMR spectroscopic investigation of the chemical shifts indicated that electron-donating

Preparation and properties of sterically protected diphosphene and fluorenylidenephosphine bearing the 2,6-di-tert-butyl-4-methoxyphenyl group

A new bulky bromobenzene, 2-bromo-1,3-di-tert-butyl-5-methoxybenzene, was prepared and utilized to preparations of the corresponding diphosphene and fluorenylidenephosphine including low-coordinate phosphorus atom(s). An electronic perturbation of the p-m

SOME NEW PROTECTIVE GROUPS FOR STABILIZING LOW COORDINATED PHOSPHORUS COMPOUNDS

Sterically stabilized diphosphenes and 1,3-diphosphaallenes by 2,4-di-t-butylphenyl or 2,4,6-tri-t-pentylphenyl groups were prepared.

A VERSATILE PREPARATION OF 2,6-DI-t-BUTYLBROMOBENZENE. APPLICATION TO STERIC PROTECTION FOR ORGANOPHOSPHORUS COMPOUNDS IN LOW COORDINATION STATES

2,6-di-t-butylbromobenzene (5) was prepared from 2,4,6-tri-t-butyl-bromobenzene by ipso nitration followed by reduction of the nitro group and deamination.The diphosphene (8) and 1,3-diphosphaallene (10) were prepared.