19715-31-2Relevant academic research and scientific papers
Preparation and properties of phosphaethynes bearing bulky aryl groups with electron-donating substituents at the para position
Toyota, Kozo,Kawasaki, Subaru,Yoshifuji, Masaaki
, p. 5065 - 5070 (2007/10/03)
Phosphaethynes bearing a 2,6-di-tert-butyl-4-(dimethylamino)phenyl, 2,6-di-tert-butyl-4-methoxyphenyl, or 2,6-di-tert-butylphenyl group were prepared. A 31P NMR spectroscopic investigation of the chemical shifts indicated that electron-donating
SOME NEW PROTECTIVE GROUPS FOR STABILIZING LOW COORDINATED PHOSPHORUS COMPOUNDS
Yoshifuji, Masaaki,Sasaki, Shigeru,Shiomi, Daisuke,Niitsu, Takashi,Inamoto, Naoki
, p. 325 - 328 (2007/10/02)
Sterically stabilized diphosphenes and 1,3-diphosphaallenes by 2,4-di-t-butylphenyl or 2,4,6-tri-t-pentylphenyl groups were prepared.
A VERSATILE PREPARATION OF 2,6-DI-t-BUTYLBROMOBENZENE. APPLICATION TO STERIC PROTECTION FOR ORGANOPHOSPHORUS COMPOUNDS IN LOW COORDINATION STATES
Yoshifuji, Masaaki,Niitsu, Takashi,Shiomi, Daisuke,Inamoto, Naoki
, p. 5433 - 5436 (2007/10/02)
2,6-di-t-butylbromobenzene (5) was prepared from 2,4,6-tri-t-butyl-bromobenzene by ipso nitration followed by reduction of the nitro group and deamination.The diphosphene (8) and 1,3-diphosphaallene (10) were prepared.
