127104-39-6

Basic information

• Product Name: N-α-methyl benzyl-O-benzoyl hydroxylamine hydrochloride
• Synonyms: N-α-methyl benzyl-O-benzoyl hydroxylamine hydrochloride
• CAS NO: 127104-39-6
• Molecular Weight: 277.751
• Mol File: 127104-39-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-α-methyl benzyl-O-benzoyl hydroxylamine hydrochloride(CAS DataBase Reference)
• NIST Chemistry Reference: N-α-methyl benzyl-O-benzoyl hydroxylamine hydrochloride(127104-39-6)
• EPA Substance Registry System: N-α-methyl benzyl-O-benzoyl hydroxylamine hydrochloride(127104-39-6)

Safety Data

• Hazardous Substances Data: 127104-39-6(Hazardous Substances Data)

Upstream product

• 20989-17-7 Phenylglycinol 
• 94-36-0 dibenzoyl peroxide 
• 2835-06-5 phenylglycin 
• 6097-58-1 ethyl 2-phenyl-2-aminoacetate 

Downstream Products

• 98-86-2 acetophenone 
• 127104-51-2 (R*,R*)-diethyl N,N-bis(1-phenylethyl)amino phosphate 
• 127104-52-3 (R*,S*)-diethyl N,N-bis(1-phenylethyl)amino phosphate 
• 126927-41-1 (R*,R*)-N-hydroxy-N-(1-phenylethyl)-1-phenylethanamine 
• 127180-95-4 (R*,S*)-N-hydroxy-N-(1-phenylethyl)-1-phenylethanamine 
• 10024-74-5 (R*,R*)-N-(1'-phenylethyl)-1-phenylethylamine 
• 21003-57-6 (R,S)-bis(1-phenylethyl)amine 
• 84388-95-4 N-benzylidene-1-phenylethanamine N-oxide 
• 127180-97-6 (+/-)-N-(2-methylpropylidene)-1-phenylethanamine N-oxide 
• 127104-27-2 N-ethylidene-1-phenylethanamine N-oxide 
• 86613-78-7 N-formyl-N-α-phenylethylhydroxylamine 
• 61077-21-2 N-acetyl-N-α-phenylethyl-hydroxylamine 
• 86613-73-2 N-Benzoyloxy-N-(1-phenyl-ethyl)-formamide 
• 2912-98-3 N-(1-phenyl-ethyl)-hydroxylamine 

Relevant articles and documents

Diastereoselectivity of Organometallic Additions to Nitrones Bearing Sterogenic N-Substituents

The diastereoselectivity of organometallic additions to nitrones bearing stereogenic α-arylethyl, β-methoxyalkyl, and β-(silyloxy)alkyl substituents on nitrogen has been investigated.High and complementary diastereoselectivity (90-94percent) was observed in the additions of Grignard reagents to nitrones (e.g. 22 and 23) bearing the potentially chelating β-methoxyalkyl group.However, the opposite selectivity resulted from the reaction of methylmagnesium bromide with the corresponding silyl ether (27).The relative stereochemistry of selected hydroxylamine adducts wasestablished by reduction of their phosphate and carbonate derivatives to known amines (37a,b and 39), by periodate cleavage of a β-hydroxy hydroxylamine (41b), and by various correlations (Scheme II).The high facial diastereoselectivity observed with the N-(β-methoxyalkyl)nitrones is explained by a simple chelation model (Scheme III).