127225-15-4Relevant academic research and scientific papers
A Rapid Method for the Synthesis of Water-soluble Platinum(II) Amine and Pyridine Complexes
Souchard, Jean-Pierre,Wimmer, Franz L.,Ha, Tam T. B.,Johnson, Neil P.
, p. 307 - 310 (1990)
Seventeen cis- complexes (am = methylamine, cycloalkylamines, substituted pyridines, aniline, or benzylamine; 2am = 2,2'-bipyridyl) were synthesized by reaction of cis- with silver nitrate in acetone.The reaction was rapid (5-20 min at room temperature) with a yield of about 85percent.The complexes appear to be stable in acetone with respect to isomerization.Thus, after 1 h at 25 degC acetone solutions of cis- (am = cyclohexylamine or 4-methylpyridine; X = I or ONO2) showed no isomerization judging by 1H n.m.r. spectroscopy of these compounds and their corresponding trans isomers.
