A Rapid Method for the Synthesis of Water-soluble Platinum(II) Amine and Pyridine Complexes

DOI: 10.1039/DT9900000307

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 307 - 310 (1990)

Update date:2022-08-03

Topics:

Authors:

Souchard, Jean-Pierre

Wimmer, Franz L.

Ha, Tam T. B.

Johnson, Neil P.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9900000307

Seventeen cis- complexes (am = methylamine, cycloalkylamines, substituted pyridines, aniline, or benzylamine; 2am = 2,2'-bipyridyl) were synthesized by reaction of cis- with silver nitrate in acetone.The reaction was rapid (5-20 min at room temperature) with a yield of about 85percent.The complexes appear to be stable in acetone with respect to isomerization.Thus, after 1 h at 25 degC acetone solutions of cis- (am = cyclohexylamine or 4-methylpyridine; X = I or ONO2) showed no isomerization judging by 1H n.m.r. spectroscopy of these compounds and their corresponding trans isomers.

Full text of DOI:10.1039/DT9900000307

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:cis-bis(4-hydroxycyclohexylamine)diiodoplatinum(II)

Cas No:127225-15-4

R&D Labs maybe for 127225-15-4

Yingkou Sanzheng Organic Chemical Co. Ltd.

Contact:+86-417-3638818

Address:25 Gengxinli Village, Daqing Road, Yingkou, Liaoning, China
Chemvon Biotechnology Co. Ltd.

website:http://www.chemvon.com

Contact:86-21-58550039;86-21-31268550-8004

Address:Suite B-10#, 6999 Chuansha Road, Pudong District, Shanghai 201202, China
Meryer (Shanghai) Chemical Technology Co., Ltd.

website:http://www.meryer.com/cn/index/

Contact:+86-755-86170518

Address:Minhang,Shanghai, China
Shanghai Yurui Biotechnology(Anyang) Pharmaceutical Co., Ltd

Contact:+86-0372-3662335 +86-0372-3661988

Address:hanling industrial park anyang
Hangzhou yi lu biont technology Co., LTD

Contact:+86-571-88152630

Address:Hangzhoushi HuafengRoad Yicheng3Building1001room.

Relevant to this article

A simple and effective synthesis of benzolactones and benzolactams by noncatalytic benzylic oxidation of cyclic benzylic ethers and N-protected cyclic benzylic amines with sodium chlorite as an oxidant

Doi:10.1055/s-0032-1316747
(2012)
Functionalization of 'kite' shaped styryl end-capped benzodithiophene with ketone groups: Synthesis, characterization and properties

Doi:10.1016/j.tet.2011.01.006
(2011)
Lewis acid catalyzed benzylic C-H bond functionalization of azaarenes: Addition to enones

Doi:10.1021/ol200217y
(2011)
Imitating micelles as a way to control coordination self-assembly: Cage-polymer switching directed rationally by solvent polarity or pH

Doi:10.1039/c0cc04196c
(2011)
Synthesis, hybridization characteristics, and fluorescence properties of oligonucleotides modified with nucleobase-functionalized locked nucleic acid adenosine and cytidine monomers

Doi:10.1021/jo500994c
(2014)
2-Amino-3,4,5-Trimethoxybenzophenones as Potent Tubulin Polymerization Inhibitors

Doi:10.1002/cmdc.201000479
(2011)

Article Doi