A Rapid Method for the Synthesis of Water-soluble Platinum(II) Amine and Pyridine Complexes

DOI: 10.1039/DT9900000307

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 307 - 310 (1990)

Update date:2022-08-03

Topics:

Authors:

Souchard, Jean-Pierre

Wimmer, Franz L.

Ha, Tam T. B.

Johnson, Neil P.

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Article abstract of DOI:10.1039/DT9900000307

Seventeen cis- complexes (am = methylamine, cycloalkylamines, substituted pyridines, aniline, or benzylamine; 2am = 2,2'-bipyridyl) were synthesized by reaction of cis- with silver nitrate in acetone.The reaction was rapid (5-20 min at room temperature) with a yield of about 85percent.The complexes appear to be stable in acetone with respect to isomerization.Thus, after 1 h at 25 degC acetone solutions of cis- (am = cyclohexylamine or 4-methylpyridine; X = I or ONO2) showed no isomerization judging by 1H n.m.r. spectroscopy of these compounds and their corresponding trans isomers.

Full text of DOI:10.1039/DT9900000307

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