127430-84-6

Basic information

• Product Name: Benzene, 1-(chloromethyl)-2,3,4,5-tetramethoxy-6-methyl-
• CAS NO: 127430-84-6
• Molecular Formula: C12H17ClO4
• Molecular Weight: 260.718
• Mol File: 127430-84-6.mol
• Article Data: 14

Chemical Properties

• CAS DataBase Reference: Benzene, 1-(chloromethyl)-2,3,4,5-tetramethoxy-6-methyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-(chloromethyl)-2,3,4,5-tetramethoxy-6-methyl-(127430-84-6)
• EPA Substance Registry System: Benzene, 1-(chloromethyl)-2,3,4,5-tetramethoxy-6-methyl-(127430-84-6)

Safety Data

• Hazardous Substances Data: 127430-84-6(Hazardous Substances Data)

Upstream product

• 6443-69-2 3,4,5-trimethoxytoluene 
• 86-81-7 3,4,5-trimethoxy-benzaldehyde 
• 72326-72-8 2-bromo-3,4,5-trimethoxy-1-methylbenzene 
• 3066-90-8 2,3-dimethoxy-5-methylbenzene-1,4-diol 
• 605-94-7 2,3-Dimethoxy-5-methyl-1,4-benzoquinone 
• 50-00-0 formaldehyd 
• 35896-58-3 2,3,4,5-tetramethoxytoluene 

Downstream Products

• 202843-56-9 2-chloromethyl-5,6-dimethoxy-3-methyl-[1,4]benzoquinone 
• 89048-25-9 2,3,4,5-tetramethoxy-6-methyl benzaldehyde 
• 84055-96-9 2-hydroxymethyl-5,6-dimethoxy-3-methyl-[1,4]benzoquinone 
• 178262-70-9 2,3,4,5-tetramethoxy-6-methylphenylmethanol 
• 127431-10-1 2-(4-benzoyl-piperazin-1-ylmethyl)-5,6-dimethoxy-3-methyl-[1,4]benzoquinone 
• 1341217-29-5 phenyl-[4-(2,3,4,5-tetramethoxy-6-methyl-benzyl)-piperazin-1-yl]-methanone 
• 84056-01-9 2,3-dimethoxy-5-(methoxymethyl)-6-methylcyclohexa-2,5-diene-1,4-dione 
• 1340548-40-4 2-[(2-hydroxyethoxy)methyl]-5,6-dimethoxy-3-methylcyclohexa-2,5-diene-1,4-dione 
• 1340548-39-1 2-(ethoxymethyl)-5,6-dimethoxy-3-methylcyclohexa-2,5-diene-1,4-dione 
• 1340548-38-0 2-(2,3,4,5-tetramethoxy-6-methylbenzyloxy)ethanol 
• 1340548-36-8 1,2,3,4-tetramethoxy-5-(methoxymethyl)-6-methylbenzene 
• 4370-61-0 ubiquinone ⁽²⁵⁾ 
• 1065-31-2 All-Trans Coenzyme Q₆ 
• 842162-36-1 1-[4-(2,3,4,5-tetramethoxy-6-methyl-benzyl)-phenoxy]-butan-2-one 

Relevant articles and documents

Allylated aromatics via Ni-catalyzed couplings of benzylic chlorides and vinylic organometallics

Hydroalumination and hydrozirconation of alkynes lead to vinylic organometallics which react with benzylic chlorides at room temperature under the influence of in situ-generated, catalytic quantities of (presumably) Ni(O), to afford allylated aromatics in good yields.

Organoiridium-quinone conjugates for facile hydrogen peroxide generation

An organoiridium complex bearing a quinone moiety was shown to significantly accelerate the rate of H2O2 formation in the presence of air and sodium formate at low catalyst concentrations. This reaction is proposed to operate through a synergistic mechanism involving transfer hydrogenation catalysis and radical chemistry. Our bifunctional iridium complex could potentially be used in anti-cancer chemotherapy or other applications requiring rapid generation of reactive oxygen species. This journal is

Practical synthesis of 2,3-dimethoxy-5-hydroxymethyl-6-methyl-1,4-benzoquinone

2,3-dimethoxy-5-hydroxymethyl-6-methyl-1,4-benzoquinone (V) was prepared with a 75 % yield by means of a reaction sequence starting from 2,3,4,5-tetramethoxytoluene via Blanc chloromethylation reaction, Kornblum oxidation, NaBH4 reduction and c