1276111-26-2

Basic information

• Product Name: [1,1′-biphenyl]-4-yl(mesityl)iodonium trifluoromethanesulfonate
• Synonyms: [1,1′-biphenyl]-4-yl(mesityl)iodonium trifluoromethanesulfonate
• CAS NO: 1276111-26-2
• Molecular Weight: 548.365
• Mol File: 1276111-26-2.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: [1,1′-biphenyl]-4-yl(mesityl)iodonium trifluoromethanesulfonate(CAS DataBase Reference)
• NIST Chemistry Reference: [1,1′-biphenyl]-4-yl(mesityl)iodonium trifluoromethanesulfonate(1276111-26-2)
• EPA Substance Registry System: [1,1′-biphenyl]-4-yl(mesityl)iodonium trifluoromethanesulfonate(1276111-26-2)

Safety Data

• Hazardous Substances Data: 1276111-26-2(Hazardous Substances Data)

Upstream product

• 1591-31-7 4-iodo-biphenyl 
• 108-67-8 1,3,5-trimethyl-benzene 
• 1493-13-6 trifluorormethanesulfonic acid 

Downstream Products

• 27644-00-4 2-([1,1'-biphenyl]-4-yl)-1-phenylethanone 
• 3073-03-8 2-phenyltriphenylene 
• 1204296-02-5 4-(1,1-difluoroethyl)-1,1’-biphenyl 

Relevant articles and documents

N1- and N3-Arylations of Hydantoins Employing Diaryliodonium Salts via Copper(I) Catalysis at Room Temperature

Copper(I)-catalyzed N-arylation (both N1- and N3-) of hydantoins with diaryliodonium salts as aryl partners at room temperature is reported. The transformation allows diverse scopes on both hydantoins and diaryliodonium salts deliver

Catalyst-Free Arylation of Tertiary Phosphines with Diaryliodonium Salts Enabled by Visible Light

The visible-light-induced arylation of tertiary phosphines with aryl(mesityl)iodonium triflates to produce the quaternary phosphonium salts occurs under mild, metal, and catalyst-free conditions. Photo-excited EDA complexes between diaryliodonium salts an

Copper-mediated trifluoromethylation of diaryliodonium salts with difluoromethyltriflate

The reaction of diaryliodonium salts with difluoromethyltriflate in the presence of TBAT and CuTC gave the corresponding trifluoromethylated arenes in moderate yields. Compared to other difluorocarbene-derived trifluoromethylation reactions, the current one proceeded at mild reaction conditions (room temperature) within short reaction time (5 min).