Tetrahedron Letters p. 6679 - 6682 (1989)
Update date:2022-08-02
Topics:
Franck-Neumann, Michel
Martina, Daniel
Heitz, Marie-Paule
Formyl-TMM (Iron)tricarbonyl 3 reacts with a high diastereoselectivity with organozinc derivatives to Iron stabilized TMM-alcohols.These are decomplexed, under partial hydrogenation, by photolysis in acetic acid to give allylic and homoallylic isoprenoic alcohols.Starting from the optically active complex (+)-3, this allows a rapid synthesis of (R)-(-)-Ipsdienol of high ee.
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(1989)Doi:10.1007/s10870-010-9763-1
(2010)Doi:10.1002/hlca.19890720811
(1989)Doi:10.1002/chem.201002569
(2011)Doi:10.1016/0022-328X(90)80062-5
(1990)
