127844-60-4

Upstream product

• 144221-12-5 (E)-3-(4-methoxyphenyl)-1-(2-(phenylsulfonylamine)phenyl)prop-2-en-1-one 
• 130820-59-6 (E)-1-(2-aminophenyl)-3-(4-methoxyphenyl)prop-2-en-1-one 
• 127844-63-7 N-{2-[2,3-Dibromo-3-(4-methoxy-phenyl)-propionyl]-phenyl}-benzenesulfonamide 
• 127844-65-9 N-{2-[2-Bromo-3-methoxy-3-(4-methoxy-phenyl)-propionyl]-phenyl}-benzenesulfonamide 
• 551-93-9 2-aminoacetophenone 
• 123-11-5 4-methoxy-benzaldehyde 
• 98-09-9 benzenesulfonyl chloride 

Relevant academic research and scientific papers

A Novel Aryl Rearrangement Reaction. Part 3. 2-Aryl Rearrangement in Azaflavanones

An aryl shift was observed when the trimethylsilyl enol ethers of azaflavanones were treated with iodosobenzeene-boron trifluoride, yielding aza-analogues of isoflavones and quinoline derivatives.

Chalcone derivatives as precursors of 1,2,3,4-tetrahydro-4-quinolones

2-Aryl-1,2,3,4-tetrahydro-4-quinolones were synthesised from 2′-amino-4-methoxychalcone and its 2′-benzenesulphonamido derivative by acid and base catalysis, respectively. The α,β-dibromo and α-bromo-β-methoxy derivatives of 2′-benzenesulphonamido-4-methoxydihydrochalcone cyclised to 2-aryl-3-bromo-1,2,3,4-tefrahydro-4-quinolones as did the corresponding α-bromochalcones. 2′-Amino-4-methoxychalcone formed a stable epoxide.