127940-85-6

Upstream product

• 18245-72-2 S-phenylthiopropionate 
• 57768-35-1 1-(phenylthio)-1-cyclohexanecarboxaldehyde 

Downstream Products

• 127941-09-7 N-((2S,3S)-3-Cyclohex-1-enyl-2-methyl-3-phenylsulfanyl-propyl)-4-methyl-benzenesulfonamide 
• 127940-96-9 (2RS,3SR)-N-<3-hydroxy-2-methyl-3-<1-(phenylthio)cyclohexyl>propyl>tosylamide 
• 127941-02-0 (3R,4R)-3-Methyl-4-phenylsulfanyl-1-(toluene-4-sulfonyl)-1-aza-spiro[4.5]decane 
• 127941-05-3 1-((2R,3R)-3-Cyclohex-1-enyl-2-methyl-3-phenylsulfanyl-propyl)-3-phenyl-urea 
• 127940-92-5 (2RS,3SR)-N-<3-hydroxy-2-methyl-3-<1-(phenylthio)cyclohexyl>propyl>-N'-phenylurea 
• 127940-98-1 (3R,4R)-3-Methyl-4-phenylsulfanyl-1-aza-spiro[4.5]decane-1-carboxylic acid phenylamide 
• 127941-00-8 (3R,4R)-3-Methyl-4-phenylsulfanyl-1-aza-spiro[4.5]decane-1-carboxylic acid ethyl ester 
• 127941-07-5 ((2R,3R)-3-Cyclohex-1-enyl-2-methyl-3-phenylsulfanyl-propyl)-carbamic acid ethyl ester 
• 127940-94-7 (2RS,3SR)-ethyl N-<3-hydroxy-2-methyl-3-<1-(phenylthio)cyclohexyl>propyl>carbamate 
• 127940-88-9 (2RS,3RS)-3-(cyclohex-1-enyl)-2-methyl-3-(phenylthio)propylamine 
• 127940-84-5 (1SR,2RS)-3-amino-2-methyl-1-<1-(phenylthio)cyclohexyl>propan-1-ol 
• 127941-04-2 (2RS,3RS)-N-<3-(1-cyclohex-2-enyl)-2-methyl-3-(phenylthio)propyl>acetamide 
• 127940-91-4 (2RS,3SR)-N-<3-hydroxy-2-methyl-3-<1-(phenylthio)cyclohexyl>propyl>acetamide 

Relevant academic research and scientific papers

STEREOCONTROLLED AMIDOCYCLISATIONS WITH PHENYLTHIO MIGRATION

Rearrangement of β-hydroxysulphides proceeds through an episulphonium ion which can be captured intramolecularly by the nitrogen atom of carbamates, ureas, or sulphonamides to give single diastereoisomers of pyrrolidines.With a free amine no capture takes