127983-46-4Relevant articles and documents
Nitrone Cycloadditions: Synthesis of (+/-)-Andrachamine
Carruthers, William,Coggins, Peter,Weston, John B.
, p. 2323 - 2327 (2007/10/02)
The usefulness of the cycloaddition of alkenes to 2-alkyl-2,3,4,5-tetrahydropyridine oxides for the preparation of trans-2,6-dialkylpiperidines is confirmed by a stereoselective synthesis of (+/-)-andrachamine.Peroxy acid oxidation of 9-oxa-1-azabicyclononanes does not lead regioselectively to the corresponding 2-alkyl-2,3,4,5-tetrahydropyridine oxide, as had previously been claimed.