1281971-17-2Relevant academic research and scientific papers
Chemo-selective Rh-catalysed hydrogenation of azides into amines
Galan, M. Carmen,Ghirardello, Mattia,Ledru, Helene,Sau, Abhijit
, (2020)
Rh/Al2O3 can be used as an effective chemo-selective reductive catalyst that combines the mild conditions of catalytic hydrogenation with high selectivity for azide moieties in the presence of other hydrogenolysis labile groups such as benzyl and benzyloxycarbonyl functionalities. The practicality of this strategy is exemplified with a range of azide-containing carbohydrate and amino acid derivatives.
Synthesis and characterization of monosaccharide derivatives and application of sugar-based prolinamides in asymmetric synthesis
Agarwal, Jyoti,Peddinti, Rama Krishna
, p. 6390 - 6406,17 (2020/09/16)
For the first time, the β-anomer of N-acetylglucosamine derivative methyl 2-acetamido-3,4,6-tri-O-benzyl-2-deoxy-β-D-glucopyranoside (9b) was synthesized, isolated, and used in the synthesis of sugar-based primary amine 4b. Sugar-based primary amine 5a, a
Glucosamine-based primary amines as organocatalysts for the asymmetric aldol reaction
Agarwal, Jyoti,Peddinti, Rama Krishna
supporting information; experimental part, p. 3502 - 3505 (2011/06/21)
Glucosamine derivatives have been synthesized starting from commercially available N-acetyl-D-glucosamine/glucosamine hydrochloride and have been employed successfully as efficient organocatalysts for the direct asymmetric aldol reaction between cyclohexa
