128316-64-3

Upstream product

• 67-56-1 methanol 
• 141109-82-2 2-hydroxy-3-(4-benzyloxyphenyl)propanoic acid 
• 60871-49-0 Methyl 3-(p-benzyloxyphenyl)-2-chloropropanoate 
• 6373-46-2 p-benzyloxyaniline 
• 154722-74-4 methyl 2-oxo-3-(4-hydroxyphenyl)propionate 
• 156-39-8 4-hydroxyphenylpiruvic acid 
• 100-39-0 benzyl bromide 
• 51095-47-7 methyl 3-(4-hydroxyphenyl)-2-hydroxypropionate 

Downstream Products

• 544703-50-6 t-butyl 3-p-benzyloxyphenyl-2-acetyloxypropionate 
• 494760-18-8 t-butyl 3-p-benzyloxyphenyl-2-hydroxypropionate 
• 478701-11-0 methyl 2-(6'-O-acetyl-2',3',4'-tri-O-t-butyldimethylsilyl-β-D-galactopyranosyloxy)-3-p-t-butyldimethylsiloxyphenyl propionate 
• 478701-17-6 methyl 2-(2',3',4'-tri-O-t-butyldimethylsilyl-β-D-galactopyranosyloxy)-3-p-t-butyldimethylsiloxyphenyl propionate 
• 478701-09-6 methyl 2-(2',3',4'-tri-O-acetyl-6'-O-benzyl-β-D-galactopyranosyl-oxy)-3-p-acetyloxyphenyl propionate 
• 478701-16-5 methyl 2-(6'-O-benzyl-β-D-galactopyranosyloxy)-3-p-hydroxyphenyl propionate 
• 77573-21-8 methyl 3-p-acetoxyphenyl-2-hydroxy propionate 
• 478701-12-1 methyl (Z)-2-(6'-O-acetyl-2',3',4'-tri-O-t-butyldimethylsilyl-β-D-galactopyranosyloxy)-3-p-t-butyldimethylsiloxyphenyl acrylate 
• 478701-19-8 methyl (Z)-2-(2',3',4'-tri-O-t-butyldimethylsilyl-β-D-galactopyranosyloxy)-3-p-t-butyldimethylsiloxyphenyl acrylate 
• 478701-13-2 (Z)-3-[4-(tert-Butyl-dimethyl-silanyloxy)-phenyl]-2-[(2S,3R,4S,5S,6S)-3,4,5-tris-(tert-butyl-dimethyl-silanyloxy)-6-formyl-tetrahydro-pyran-2-yloxy]-acrylic acid methyl ester 
• 864070-64-4 methyl 3-p-acetoxyphenyl-2-t-butyldimethylsiloxy propionate 

Relevant academic research and scientific papers

Syntheses and novel bioactivities of artificial leaf-opening substances of Lespedeza cuneata G. Don, designed for the bioorganic studies of nyctinasty

Potassium lespedezate (1) is the leaf-opening substance of a nyctinastic plant, Lespedeza cuneata G. Don. We have synthesized two sugar-derivatives of 1, potassium galactolespedezate (4) and mannolespedezate (6). Both 4 and 6 were quite effective for the leaf-opening of Cassia. mimosoides at 8 x 10-7 M, as strong as 1. However, 1 kept the leaf open only for a few days; on the other hand, 4 and 6 kept the leaf open after a week at that concentration. Additionally, remarkable difference was observed in the rate of enzymatic hydrolysis of natural and artificial leaf-opening sustance by using commercially available β-glucosidase. Therefore, 4 and 6 would not be hydrolized in the plant body, and are potentially useful molecular probes for the studies of the control of the nyctinastic leaf-movement by a biological clock.

Anomalous fluorinations of 3-aryl-2-hydroxypropanoic esters by diethylaminosulfur trifluoride (DAST)

Treatment of 3-aryl-2-hydroxypropanoic esters 8 with diethylaminosulfur trifluoride (DAST) gives considerable amounts of rearranged 2-aryl-3-fluoropropanoic esters 12 together with the expected products 11. The extent of rearrangement is dependent on solv