128802-95-9Relevant academic research and scientific papers
Self-assembly of chelating, bridging N, N, N donor ligands and Cu(I), Cu(II), Cd(II), Hg(II): Molecular box versus coordination polymer
Tabatabaei, Robabehsadat,Dehghanpour, Saeed,Simpson, Jim,Lipkowski, Janusz
, p. 9 - 19 (2015)
Three flexible chelating and bridging ligands, (E)-N-(pyridin-2-ylmethylene)-1-(pyridin-3-yl)methanamine (L1), 1-(pyridine-2-yl)-N-(pyridin-3-ylmethyl)methanamine (L1′), (E)-N-(pyridin-2-ylmethylene)-1-(pyridin-4-yl)methanamine (Lsu
Chemoselective hydrogenation of nitriles to secondary or tertiary amines catalyzed by aqueous-phase catalysts supported on hexagonal mesoporous silica
Nait Ajjou, Abdelaziz,Robichaud, André
, (2018/09/12)
The first supported aqueous-phase catalyst for the hydrogenation of nitriles is revealed. The catalyst prepared from Pd(PhCN)2Cl2, water-soluble ligand 2,2′-biquinoline-4,4′-dicarboxylic acid dipotassium salt and mesoporous silica is a highly efficient catalyst for the selective formation of secondary or tertiary amines from aromatic or aliphatic nitriles. The catalytic system is stable and can be recycled and reused three times without loss of activity and selectivity. This environmentally friendly process is, in addition, an attractive alternative to many homogeneous and heterogeneous catalysts because of its easy preparation and the moderate operational conditions under which it is highly active.
Zinc sensors with lower binding affinities for cellular imaging
Kim, Jin Hoon,Hwang, In Hong,Jang, Seung Pyo,Kang, Juhye,Kim, Sumi,Noh, Insup,Kim, Youngmee,Kim, Cheal,Harrison, Roger G.
, p. 5500 - 5507 (2013/06/05)
Zinc sensors based on 2,3-dipicolylamine (DPA) and quinoline have been synthesized. They fluoresced in the presence of Zn2+ and remained fluorescent when other metal ions were present. Fluorescence enhancement of the sensors was not seen for mo
