128924-06-1

Basic information

• Product Name: 4'-phenoxy-4-nitrobiphenyl
• Synonyms: 4'-phenoxy-4-nitrobiphenyl
• CAS NO: 128924-06-1
• Molecular Weight: 291.306
• Mol File: 128924-06-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 4'-phenoxy-4-nitrobiphenyl(CAS DataBase Reference)
• NIST Chemistry Reference: 4'-phenoxy-4-nitrobiphenyl(128924-06-1)
• EPA Substance Registry System: 4'-phenoxy-4-nitrobiphenyl(128924-06-1)

Safety Data

• Hazardous Substances Data: 128924-06-1(Hazardous Substances Data)

Upstream product

• 92491-67-3 tert-butyl 2-(4-nitrophenyl)hydrazine-1-carboxylate 
• 100-16-3 4-nitrophenylhydrazone 
• 17672-27-4 4-hydrazinobenzonitrile 
• 101-84-8 diphenylether 
• 92722-14-0 tert-butyl 2-(4-nitrophenyl)diazenecarboxylate 
• 1354828-66-2 tert-butyl 2-(4-cyanophenyl)diazene-1-carboxylate 
• 1528-74-1 4,4'-dinitrobiphenyl 
• 100-67-4 potassium phenolate 

Relevant articles and documents

Nucleophilic substitutions and radical reactions of phenylazocarboxylates

tert-Butyl phenylazocarboxylates are versatile building blocks for synthetic organic chemistry. Nucleophilic substitutions of the benzene ring proceed with aromatic amines and alcohols under mild conditions. The attack of aliphatic amines may be directed to the aromatic core as well as to the carbonyl unit leading to azocarboxamides. The benzene ring can further be modified through radical reactions, in which the tert-butyloxycarbonylazo group enables the generation of aryl radicals at either elevated temperatures or under acidic conditions. Radical reactions include oxygenation, halogenation, carbohalogenation, carbohydroxylation, and aryl-aryl coupling.