128970-59-2

Basic information

• Product Name: Acetic acid (E)-2-chloro-2-iodo-1-phenyl-vinyl ester
• Synonyms: Acetic acid (E)-2-chloro-2-iodo-1-phenyl-vinyl ester
• CAS NO: 128970-59-2
• Molecular Weight: 322.53
• Mol File: 128970-59-2.mol

Chemical Properties

• CAS DataBase Reference: Acetic acid (E)-2-chloro-2-iodo-1-phenyl-vinyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Acetic acid (E)-2-chloro-2-iodo-1-phenyl-vinyl ester(128970-59-2)
• EPA Substance Registry System: Acetic acid (E)-2-chloro-2-iodo-1-phenyl-vinyl ester(128970-59-2)

Safety Data

• Hazardous Substances Data: 128970-59-2(Hazardous Substances Data)

Upstream product

• 3240-34-4 [bis(acetoxy)iodo]benzene 
• 932-88-7 1-iodo-2-phenylethyne 
• 536-74-3 phenylacetylene 
• 1483-82-5 phenylethynyl chloride 
• 64-19-7 acetic acid 

Relevant articles and documents

Selective oxygenation of alkynes: A direct approach to diketones and vinyl acetate

Arylalkynes can be converted into α-diketones with the use of a copper catalyst, and also be transformed into vinyl acetates under metal-free conditions, both in the presence of PhI(OAc)2 as an oxidant at room temperature. A series of substituted α-diketones were prepared in moderate to good yields. A variety of vinyl halides could be regio- and stereo-selectively synthesized under mild conditions, and I, Br and Cl could be all easily embedded into the alkynes. This journal is

Synthesis of 2-functionalized 1-chloro-1-iodo-1-alkenes from 1-chloro-1-alkynes and IPy2BF4

1-Chloro-1-alkynes react with bis(pyridine)iodine(I)tetrafluoroborate (1) and nucleophiles (AcOH, HCOOH, Cl, Br, I) to give, in a regio- and stereoselective addition, 2-functionalized 1-chloro-1-iodo-1-alkenes.