1290636-90-6Relevant articles and documents
Kinetic study on aminolysis of 4-chloro-2-nitrophenyl X-substituted-benzoates in Acetonitrile and in 80 mol % H2O/20 mol % DMSO: Effect of medium on reactivity and reaction mechanism
Kim, Ha-Ram,Um, Tae-Il,Kim, Min-Young,Um, Ik-Hwan
, p. 1128 - 1132 (2014/05/06)
A kinetic study on aminolysis of 4-chloro-2-nitrophenyl X-substituted-benzoates (6a-i) in MeCN is reported. The Hammett plot for the reactions of 6a-i with piperidine consists of two intersecting straight lines, while the Yukawa-Tsuno plot exhibits an exc
N-(2-hydroxyaryl)benzamide synthesis from 2-nitroaryl benzoates via an Indium-mediated reduction-migration reaction
Lee, Hyejeong,Kim, Minki,Jun, Young Moo,Kim, Byeong Hyo,Lee, Byung Min
scheme or table, p. 158 - 167 (2011/10/08)
A one-pot reduction-triggered N-(2-hydroxyaryl)benzamide synthesis from 2-nitroaryl benzoate substrates was investigated. In the presence of indium/AcOH in THF/H2O, 2-nitroaryl benzoates produced reasonable yields of the benzo group migrated N-