54384-18-8Relevant academic research and scientific papers
Control of Diastereofacial Selectivity in the Nucleophilic Epoxidation of γ-Oxygenated α,β-Unsaturated Sulfones
Jackson, Richard F. W.,Standen, Stephen P.,Clegg, William
, p. 149 - 156 (2007/10/02)
Epoxidation of γ-oxygenated-α,β-unsaturated sulfones 6-10 with either lithium or potassium tert-butyl peroxide proceeds with moderate to high diastereoselectivity to give mixtures of the syn-2-(phenylsulfonyl)oxiranes 11-15 and the corresponding anti-2-(p
EFFECIENT 4 + 1 SYNTHESES OF HIGHLY FUNCTIONALIZED CYCLOPENTENES
Nantz, M. H.,Radisson, X.,Fuchs, P. L.
, p. 55 - 70 (2007/10/02)
Condensation of sulfone-activated methylene compounds with cis-1,4-dichloro-2-butene yields cyclopentenes.Elaboration of these cyclopentene products into highly functionalized intermediates is described.
