129144-88-3

Upstream product

• 58479-61-1 tert-butylchlorodiphenylsilane 
• 146983-20-2 methyl (2E)-2-<<(tert-butyldiphenylsilyl)oxy>methyl>-2-butenoate 
• 98837-36-6 methyl 3-hydroxy-2-methylenebutyrate 
• 33935-64-7 methyl 2-(bromomethyl)-2-butenoate 
• 28127-64-2 methyl (2E)-2-(hydroxymethyl)-2-butenoate 
• 146983-21-3 2-<<(tert-butyldiphenylsilyl)oxy>methyl>-2(Z)-butenol 

Downstream Products

• 144446-52-6 tert-Butyl-[(Z)-2-(2,2-dibromo-vinyl)-but-2-enyloxy]-diphenyl-silane 
• 129144-95-2 (2E,4E,6Z)-6-(tert-Butyl-diphenyl-silanyloxymethyl)-2-methyl-octa-2,4,6-trienoic acid methyl ester 
• 146983-22-4 methyl 4-<<(tert-butyldiphenylsilyl)oxy>methyl>-2(E),4(Z)-hexadienoate 
• 213122-62-4 (E)-4-(tert-Butyl-diphenyl-silanyloxymethyl)-hexa-1,4-dien-3-ol 
• 146983-30-4 4-{[(tert-butyldiphenylsilyl)oxy]methyl}-2(E),4(Z)-hexadienol 
• 213122-60-2 (2E,8Z,10E,16E,18E,20Z)-(S)-20-(tert-Butyl-diphenyl-silanyloxymethyl)-7-methoxymethoxy-2-methyl-9-trimethylsilanyl-docosa-2,8,10,16,18,20-hexaenoic acid allyl ester 
• 213182-19-5 (1S,2R,5R)-2-[(E)-7-(tert-Butyl-dimethyl-silanyloxy)-hept-1-enyl]-4-(tert-butyl-diphenyl-silanyloxymethyl)-1-hydroxy-5-methyl-cyclohex-3-enecarboxylic acid methyl ester 
• 144446-56-0 (1S,2R,5R)-1-(2-Benzyloxy-acetoxy)-2-[(E)-7-(tert-butyl-dimethyl-silanyloxy)-hept-1-enyl]-4-(tert-butyl-diphenyl-silanyloxymethyl)-5-methyl-cyclohex-3-enecarboxylic acid methyl ester 
• 144446-45-7 (5S,6R,9R)-3-Benzyloxy-6-[(E)-7-(tert-butyl-dimethyl-silanyloxy)-hept-1-enyl]-8-(tert-butyl-diphenyl-silanyloxymethyl)-4-methoxymethoxy-9-methyl-1-oxa-spiro[4.5]deca-3,7-dien-2-one 
• 144446-47-9 (6E,8Z,10Z)-1-(tert-butyldimethylsilyloxy)-10-[(tert-butyldiphenylsilyloxy)methyl]dodeca-6,8,10-triene 
• 213182-18-4 (6E,8Z,10Z)-8-bromo-1-(tert-butyldimethylsilyloxy)-10-[(tert-butyldiphenylsilyloxy)methyl]dodeca-6,8,10-triene 
• 213182-17-3 (6E,8Z,10Z)-8-Bromo-10-(tert-butyl-diphenyl-silanyloxymethyl)-dodeca-6,8,10-trien-1-ol 
• 144446-55-9 (2R,5S,6R,9R)-2-tert-Butyl-6-[(E)-7-(tert-butyl-dimethyl-silanyloxy)-hept-1-enyl]-8-(tert-butyl-diphenyl-silanyloxymethyl)-9-methyl-1,3-dioxa-spiro[4.5]dec-7-en-4-one 
• 146983-23-5 4-{[(tert-butyldiphenylsilyl)oxy]methyl}-2(E),4(Z)-hexadienal 

Relevant academic research and scientific papers

A Highly Diastereo- and Enantioselective Synthesis of the Top Half of Kijanolide

A highly diastereo- and enantioselective synthesis of spirotetronate 4 corresponding to the top half of kijanolide is reported.This synthesis features the novel exo-selective Diels-Alder reaction of triene 6 and the chiral, nonracemic dienophiles (R)-7 an

Diastereoselective synthesis of the top half of kijanolide

A highly diastereoselective synthesis of the top half (4) of kijanolide is described. The key step is the exo and diastereoface selective Diels-Alder reaction of triene 6 and chiral dienophile 6.