146983-30-4Relevant academic research and scientific papers
A Highly Diastereo- and Enantioselective Synthesis of the Top Half of Kijanolide
Roush, William R.,Brown, Bradley B.
, p. 2151 - 2161 (1993)
A highly diastereo- and enantioselective synthesis of spirotetronate 4 corresponding to the top half of kijanolide is reported.This synthesis features the novel exo-selective Diels-Alder reaction of triene 6 and the chiral, nonracemic dienophiles (R)-7 an
Enantioselective total synthesis of (-)-chlorothricolide via the tandem inter- and intramolecular Diels-Alder reaction of a hexaenoate intermediate
Roush, William R.,Sciotti, Richard J.
, p. 7411 - 7419 (2007/10/03)
An enantioselective total synthesis of (-)-chlorothricolide (1) has been completed via a route involving the tandem inter- and intramolecular Dieis-Alder (IMDA) reaction of hexaenoate 19 and the chiral dienophile (R)-12. This reaction, which establishes s
Diastereoselective synthesis of the top half of kijanolide
Roush,Brown
, p. 7309 - 7312 (2007/10/02)
A highly diastereoselective synthesis of the top half (4) of kijanolide is described. The key step is the exo and diastereoface selective Diels-Alder reaction of triene 6 and chiral dienophile 6.
