129213-03-2Relevant academic research and scientific papers
Regioselective SN2 reactions for rapid syntheses of azido-inositols by one-pot sequence-specific nucleophilysis
Ravi, Arthi,Hassan, Syed Zahid,Vanikrishna, Ajithkumar N.,Sureshan, Kana M.
, p. 3971 - 3973 (2017)
Triflates of myo-inositol undergo facile solvolysis in DMSO and DMF yielding SN2 products substituted with O-nucleophiles; DMF showed slower kinetics. Axial O-triflate undergoes faster substitution than equatorial O-triflate. By exploiting this
Total Synthesis of Methoxyhygromycin and Its 5-Epimer
Chida, Noritaka,Nakazawa, Keiichi,Ohtsuka, Masami,Suzuki, Minoru,Ogawa, Seiichiro
, p. 423 - 426 (2007/10/02)
Methoxyhygromycin, an antibiotic having a unique structure among the aminocyclitol antibiotics, and its 5-epimer are first synthesized.This synthesis fully confirmed the proposed structure of the antibiotic and revealed that neo-configuration of cyclitol
