129388-29-0Relevant academic research and scientific papers
Highly enantioselective allylation of α-ketoesters catalyzed by N,N′-dioxide-in(III) complexes
Zheng, Ke,Qin, Bo,Liu, Xiaohua,Feng, Xiaoming
, p. 8478 - 8483 (2007)
(Chemical Equation Presented) An efficient asymmetric allylation of α-ketoesters was catalyzed by the N,N′-dioxide-In(III) complex in excellent yields (up to 99%) and high enantioselectivities (up to 94% ee) for a variety of substrates under mild reaction
Pig Liver Esterase Catalyzed Hydrolyses of Racemic α-Substituted α-Hydroxy Esters
Moorlag, Henk,Kellogg, Richard M.,Kloosterman, Marcel,Kaptein, Bernard,Kamphuis, Johan,Schoemaker, Hans E.
, p. 5878 - 5881 (2007/10/02)
Pig liver esterase catalyzed hydrolyses of some α-substituted α-hydroxy esters give product acids and recovered esters in 9-94percent enantiomeric excess.The observed enantiomeric selectivity could be rationalized using a recently proposed active site mod
