1294009-16-7

Basic information

• Product Name: 2-(3-(4-fluorophenyl)prop-1-en-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
• Synonyms: 2-(3-(4-fluorophenyl)prop-1-en-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
• CAS NO: 1294009-16-7
• Molecular Weight: 262.132
• Mol File: 1294009-16-7.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2-(3-(4-fluorophenyl)prop-1-en-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(3-(4-fluorophenyl)prop-1-en-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane(1294009-16-7)
• EPA Substance Registry System: 2-(3-(4-fluorophenyl)prop-1-en-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane(1294009-16-7)

Safety Data

• Hazardous Substances Data: 1294009-16-7(Hazardous Substances Data)

Upstream product

• 405-99-2 para-fluorostyrene 
• 127510-50-3 1-(2,2-dibromocyclopropyl)-4-fluorobenzene 
• 70090-77-6 1-fluoro-4-(propa-1,2-dien-1-yl)benzene 
• 73183-34-3 bis(pinacol)diborane 
• 3798-61-6 1-(4-fluorophenyl)prop-2-yn-1-ol 
• 459-57-4 4-fluorobenzaldehyde 
• 1429766-96-0 2-((2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)allyl)sulfonyl)pyridine 
• 352-13-6 4-flourophenylmagnesium bromide 

Relevant articles and documents

Copper(ii)-catalyzed protoboration of allenes in aqueous media and open air

A method has been developed for the facile Cu(ii)-catalyzed protoboration of monosubstituted allenes in aqueous media under atmospheric conditions. The reaction occurs site selectively, favoring internal alkene protoboration to afford 1,1-disubstituted vinylboronic acid derivatives (up to 93?:?7) with modest to good yields. The method has been applied to a variety of phenylallene derivatives as well as alkyl-substituted allenes. This journal is

Formal regiocontrolled hydroboration of unbiased internal alkynes via borylation/allylic alkylation of terminal alkynes

In accessing trisubstituted vinyl boronates from terminal alkynes, a propargyl directing (2-pyridyl)sulfonyl group allows terminal alkynes to undergo Cu-catalyzed B2(pin)2-borylation and subsequent Cu-catalyzed allylic alkylation wit