129423-31-0

Basic information

• Product Name: Cyclopropanol, 2-(phenylmethyl)-, (1R,2R)-
• CAS NO: 129423-31-0
• Molecular Formula: C10H12O
• Molecular Weight: 148.205
• Mol File: 129423-31-0.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Cyclopropanol, 2-(phenylmethyl)-, (1R,2R)-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclopropanol, 2-(phenylmethyl)-, (1R,2R)-(129423-31-0)
• EPA Substance Registry System: Cyclopropanol, 2-(phenylmethyl)-, (1R,2R)-(129423-31-0)

Safety Data

• Hazardous Substances Data: 129423-31-0(Hazardous Substances Data)

Upstream product

• 122-97-4 3-Phenyl-1-propanol 
• 19261-37-1 2-chloro-3-phenyl-propionaldehyde 
• 1462-75-5 3-phenylpropylmagnesium bromide 
• 109-94-4 formic acid ethyl ester 
• 31729-70-1 bis(iodozinc)methane 
• 75-11-6 diiodomethane 
• 129423-29-6 [(1E)-3-phenylprop-1-en-1-yl]boronic acid 
• 129423-31-0 trans-2-benzylcyclopropanol 

Downstream Products

• 136068-13-8 S-phenyl 3-benzyl-5-oxopentanethioate 
• 129423-31-0 (1S,2S)-2-Benzyl-cyclopropanol 

Relevant articles and documents

Diasteroselective preparation of cyclopropanols using methylene bis(iodozinc)

Chemical equations presented. A diastereoselective synthesis of trans-2-substituted cyclopropanols is outlined. Bimetallic CH 2(ZnI)2 was found to react with α-chloroaldehydes to give cyclopropanols in yields of 64-89% and dr's ≥ 10:

Synthesis of 3,5-Disubstituted 1,2-Dioxolanes through the Use of Acetoxy Peroxyacetals

The synthesis of acetoxyendoperoxyacetal derivatives allowed the formation of functionalized 3,5-disubstituted 1,2-dioxolanes through the formation of reactive peroxycarbenium species under Lewis acid mediation. The introduction of a neutral nucleophile s

Asymmetric Cyclopropanation of 1-Alkenylboronic Esters and Its Application to the Synthesis of Optically Active Cyclopropanols

The first asymmetric cyclopropanation of 1-alkenylboronic esters was realized by diastereofacial selective Simmons-Smith reaction of the esters modified by enantiomerically pure diols such as tetramethyltartaramide.Subsequent oxidation of the resulting cyclopropylboronates gave optically active 2-substituted cyclopropanols in 73-94percent ee.These reactive compounds possess high synthetic potential.