129662-35-7Relevant academic research and scientific papers
Synthesis of racemic 6-deoxy-6-fluoro-chiro-inositol 2,3,5-trisphosphate
Carless,Busia
, p. 207 - 215 (2007/10/02)
The synthesis of (±)-6-deoxy-6-fluoro-chiro-inositol 2,3,5-trisphosphate (4) is reported, starting from cyclohexa-1,4-diene. A key step involved the stereospecific 1,4-addition of singlet oxygen to trans-1,2-di-O-(2-methoxyethoxymethyl)cyclohexa-3,5-diene
Total synthesis of myo-inositol polyphosphates from benzene via conduritol B derivatives
Carless, Howard A. J.,Busia, Kofi
, p. 3449 - 3452 (2007/10/02)
The four (±)-myo-inositol phosphates 1,4,5-IP3 (1), 2,4,5-IP3 (15), 1,2,4,5-IP4 (17) and 4,5-IP2 (19) have been synthesised from benzene, using the protected conduritol B (10) as the key intermediate.
TOTAL SYNTHESIS OF chiro-INOSITOL 2,3,5-TRISPHOSPHATE: A myo-INOSITOL 1,4,5-TRISPHOSPHATE ANALOGUE FROM BENZENE VIA PHOTO-OXIDATION
Carless, Howard A. J.,Busia, Kofi
, p. 1617 - 1620 (2007/10/02)
The inositol tris- and tetrakis-phosphate analogues (4) and (14) have been synthesized from benzene by a sequence including reaction of singlet oxygen with a trans-cyclohexa-3,5-diene-1,2-diol (3) derivative.
