130032-79-0Relevant academic research and scientific papers
nBu4NI-catalyzed oxidative cross-coupling of carbon dioxide, amines, and aryl ketones: access to O-β-oxoalkyl carbamates
Peng, Youbin,Liu, Juan,Qi, Chaorong,Yuan, Gaoqing,Li, Jiawei,Jiang, Huanfeng
, p. 2665 - 2668 (2017)
The first nBu4NI-catalyzed oxidative cross-coupling reaction of carbon dioxide, amines and arylketones has been successfully developed by using TBHP as the oxidant, providing an efficient, atom-economical and metal-free strategy for the synthesis of a range of O-β-oxoalkyl carbamates.
α-Metalated Tertiary Enol Carbamates. New Acyl Anion Equivalents
Sengupta, Saumitra,Snieckus, Victor
, p. 5680 - 5683 (2007/10/02)
α-Metalated enol carbamate 1g constitutes a new, conveniently generated (sec-BuLi/TMEDA/THF/-78 deg C), and well-behaved acyl anion equivalent.The utility and scope of this synthon for the preparation of a variety of useful synthetic building blocks (4, 6
