130136-43-5

Basic information

• Product Name: (R)-2-benzyl-5-methylcyclohexanone
• CAS NO: 130136-43-5
• Molecular Weight: 202.296
• Mol File: 130136-43-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (R)-2-benzyl-5-methylcyclohexanone(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-2-benzyl-5-methylcyclohexanone(130136-43-5)
• EPA Substance Registry System: (R)-2-benzyl-5-methylcyclohexanone(130136-43-5)

Safety Data

• Hazardous Substances Data: 130136-43-5(Hazardous Substances Data)

Upstream product

• 861039-86-3 1-benzyl-1,2-epoxy-4-methyl-cyclohexane 
• 100-39-0 benzyl bromide 
• 591-24-2 3-Methylcyclohexanone 
• 64-17-5 ethanol 
• 56576-59-1 2-benzylidene-5-methyl-cyclohexanone 
• 79734-53-5 trans R-(-)-2-benzylidene-5-methylcyclohexanone 
• 93-59-4 Perbenzoic acid 
• 100-52-7 benzaldehyde 
• 13368-65-5 (3R)-3-methylcyclohexanone 

Downstream Products

• 130136-46-8 (R)-8-benzyl-5-methyl-5,6,7,8-tetrahydroquinoline N-oxide 
• 130136-45-7 (R)-8-benzyl-5-methyl-5,6,7,8-tetrahydroquinoline 
• 130136-47-9 (R)-8-benzyl-5-methyl-5,6-dihydroquinoline 
• 130136-48-0 (R)-8-benzylidene-5-methyl-5,6-dihydro-(7H)-quinoline 
• 130136-44-6 (R)-6-benzyl-3-methylcyclohexanone N,N-dimethylhydrazone 

Relevant articles and documents

Highly Regioselective Monoalkylation of Ketones via Manganese Enolates. Prepared from Lithium Enolates

Li-enolates are readily converted to Mn-enolates by treatment with manganese halides.In THF, the reaction is easily and economically performed with manganese chloride at room temperature.Mn-enolates can then be regioselectively monoalkylated in good yields.The formation of di and polyalkylated products is never observed (1percent).