13021-14-2

Basic information

• Product Name: 2 4 6-TRIMETHYL-N-METHYLANILINE 97
• Synonyms: 2 4 6-TRIMETHYL-N-METHYLANILINE 97;Benzenamine,N,2,4,6-tetramethyl-;N,2,4,6-Tetramethylaniline;N,2,4,6-Tetramethylbenzenamine
• CAS NO: 13021-14-2
• Molecular Formula: C₁₀H₁₅N
• Molecular Weight: 149.2328
• Product Categories: Amines;C9 to C10;Nitrogen Compounds
• Mol File: 13021-14-2.mol
• Article Data: 11

Chemical Properties

• Boiling Point: 229 °C(lit.)
• Flash Point: 190 °F
• Appearance: Colorless to brown/Liquid
• Density: 0.935 g/mL at 25 °C(lit.)
• Vapor Pressure: 0.0465mmHg at 25°C
• Refractive Index: n20/D 1.5320(lit.)
• Storage Temp.: 2-8°C
• CAS DataBase Reference: 2 4 6-TRIMETHYL-N-METHYLANILINE 97(CAS DataBase Reference)
• NIST Chemistry Reference: 2 4 6-TRIMETHYL-N-METHYLANILINE 97(13021-14-2)
• EPA Substance Registry System: 2 4 6-TRIMETHYL-N-METHYLANILINE 97(13021-14-2)

Safety Data

• Hazard Codes: Xi,N
• Statements: 36/38-50/53
• Safety Statements: 26-60-61
• RIDADR: UN 3082 9/PG 3
• WGK Germany: 3
• Hazardous Substances Data: 13021-14-2(Hazardous Substances Data)

Usage

General Description

2 4 6-Trimethyl-N-methylaniline 97 is a chemical compound that consists of three methyl groups and a methylaniline group attached to a benzene ring. It is commonly used as a stabilizing agent in the production of rubber and plastic materials. Additionally, it can also be employed as an intermediate in the synthesis of various dyes and pigments. 2 4 6-TRIMETHYL-N-METHYLANILINE 97 is known for its high purity, with a 97% concentration, which makes it a preferred choice for applications requiring precise chemical compositions and consistent performance. However, it is important to handle this chemical with care due to its potential health hazards, including skin and eye irritation, and it should only be used in well-ventilated areas with proper protective equipment.

InChI:InChI=1/C10H15N/c1-7-5-8(2)10(11-4)9(3)6-7/h5-6,11H,1-4H3

Upstream product

• 77-78-1 dimethyl sulfate 
• 88-05-1 2,4,6-trimethylaniline 
• 40752-00-9 N-mesityl-N-methylacetamide 
• 65962-97-2 O-mesitylenesulfonyl-N-tert-butoxycarbonyl-N-methylhydroxylamine 
• 108-67-8 1,3,5-trimethyl-benzene 
• 67-56-1 methanol 
• 25370-97-2 O-(p-toluenesulfonyl)-N-methylhydroxylamine 
• 13021-15-3 2,4,6-trimethyl-N,N-dimethylaniline 
• 6784-26-5 2-isocyanato-1,3,5-trimethylbenzene 
• 155671-06-0 2,4,6,N-tetramethyl-N-nitroso-aniline 

Downstream Products

• 102550-36-7 bis-[(2,4,6,N-tetramethyl-anilino)-methyl]-peroxide 
• 5279-62-9 2-(Formyl-methylamino)-1,3,5-trimethylbenzol 
• 40752-11-2 N-Methyl-2-phenyl-N-(2,4,6-trimethyl-phenyl)-acetamide 
• 500730-66-5 (+/-)-N-(3-bromo-2,4,6-trimethyl-phenyl)-N-methyl-succinamic acid 
• 858806-01-6 N-mesityl-N-methyl-succinamic acid 
• 88-05-1 2,4,6-trimethylaniline 
• 1616604-89-7 C₁₇H₂₁NO₃S 
• 1415351-71-1 S-but-3-en-2-yl mesityl(methyl)carbamothioate 
• 1292296-29-7 imidazole-1-carboxylic acid methyl(2,4,6-trimethylphenyl)amide 
• 1292296-58-2 methyl(2,4,6-trimethylphenyl)thiocarbamic acid (S)-1-phenyl-ethyl ester 
• 1292296-35-5 1-methyl-3-[methyl(2,4,6-trimethylphenyl)carbamoyl]-3H-imidazol-1-ium iodide 

Relevant articles and documents

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Self-Immolative System for Disclosure of Reactive Electrophilic Alkylating Agents: Understanding the Role of the Reporter Group

The development of stable, efficient chemoselective self-immolative systems, for use in applications such as sensors, requires the optimization of the reactivity and degradation characteristics of the self-immolative unit. In this paper, we describe the effect that the structure of the reporter group has upon the self-immolative efficacy of a prototype system designed for the disclosure of electrophilic alkylating agents. The amine of the reporter group (a nitroaniline unit) was a constituent part of a carbamate that functioned as the self-immolative unit. The number and position of substituents on the nitroaniline unit were found to play a key role in the rate of self-immolative degradation and release of the reporter group. The position of the nitro substituent (meta- vs para-) and the methyl groups in the ortho-position relative to the carbamate exhibited an influence on the rate of elimination and stability of the self-immolative system. The ortho-methyl substituents imparted a twist on the N-C (aromatic) bond leading to increased resonance of the amine nitrogen's lone pair into the carbonyl moiety and a decrease of the leaving character of the carbamate group; concomitantly, this may also make it a less electron-withdrawing group and lead to less acidification of the eliminated β-hydrogen.

SELF-IMMOLATIVE SYSTEMS

The present invention is concerned with self-immolative recognition and/or responsive systems for electrophilic compounds, especially alkylating agents, which systems may comprise disclosure or detection of the alkylating agent. The present invention is especially concerned with non-protic triggered self-immolative systems, molecules, and methods, and in particular for detection of non- protic electrophilic agents, and especially alkylating agents, for example alkyl or benzylic halides, which may be found in pesticides or fumigants, or chemical warfare agents.