13038-12-5

Usage

InChI:InChI=1/C7H10O2/c1-3-5-6-7(8)9-4-2/h3,5-6H,1,4H2,2H3

Upstream product

• 64-17-5 ethanol 
• 626-99-3 1,3-butadiene-1-carboxylic acid 
• 107-02-8 acrolein 
• 927-80-0 1-ethoxyacetylene 
• 75-03-6 ethyl iodide 
• 7647-01-0 hydrogenchloride 
• 1071-46-1 hydrogen ethyl malonate 
• 127492-03-9 1-(phenylsulfinyl)-2,2,2-triethoxyethane 
• 107-18-6 allyl alcohol 
• 1655-07-8 ethyl 2-oxocyclohexane carboxylate 
• 7250-85-3 1,4-diethoxy-but-2-ene 
• 201230-82-2 carbon monoxide 

Downstream Products

• 108-86-1 bromobenzene 
• 92-52-4 biphenyl 
• 140863-27-0 1,3-diphenyl-1-oxo-4-pentene 
• 626-99-3 1,3-butadiene-1-carboxylic acid 
• 121143-47-3 ethyl 6-ethoxy-6-phenyl-3,5-hexadienoate 
• 121173-71-5 tricarbonyl{(1-3)-η3-(2Z)-(η1-(E)-α-ethoxybenzylidene)-4-ethoxycarbonyl-1,3-butanediyl}iron(0) 
• 121249-28-3 tricarbonyl{(1-3)-η3-(2E)-(η1-(E)-α-ethoxybenzylidene)-4-ethoxycarbonyl-1,3-butanediyl}iron(0) 
• 121173-72-6 tricarbonyl{(1-3)-η3-(2Z)-(η1-(Z)-α-ethoxybenzylidene)-4-ethoxycarbonyl-1,3-butanediyl}iron(0) 
• 581812-94-4 (E)-ethyl 3-(4-(trifluoromethyl)phenyl)but-2-enoate 
• 948-03-8 1-hydroxy-naphthalene-2-carboxylic acid methyl ester 
• 1384880-04-9 ethyl 3-(4-(trifluoromethyl)-phenyl)but-3-enoate 

Relevant academic research and scientific papers

New heteroannulation reactions of N-Alkoxybenzamides by Pd(II) Catalyzed C-H activation

A new palladium(II) catalyzed methodology for the direct synthesis of alkylidene isoindolinones from N-alkoxybenzamides is presented. Isoindolinone formation proceeds through a highly efficient and E-selective C-H activation/Heck/Aza-Wacker sequence. Subs

One-Flask, Regiospecific Conversions of Allylic Alcohols into Two-Carbon-Extended, Conjugated Dienoate Esters. Use of a New Sulfinyl Orthoester

Sixteen differently substituted primary and secondary allylic alcohols are shown to react with sulfinyl orthoacetate 1 at 100 deg C sequentially via a sigmatropic rearrangement and then a β-elimination of benzenesulfenic acid to form conjugated dienoate esters 5-13 in 45-95percent yields.This one-flask, intramolecular carbon-carbon bond-forming process represents a simple and convenient method for regiospecific γ-attachment of a two-carbon (ethoxycarbonyl)methylene unit via the synthetic equivalent of an SN2' process.Two examples are given in which rationally designed dienoates 20 and 24, prepared via this one-flask process and carrying a pendant alkene unit, undergo intramolecular 2+4 cycloaddition producing bicyclic cyclohexenes 21 and 25.