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TRIMETHYLANTIMONY(V) DICHLORIDE 96, also known as (CH3)3SbCl2, is a highly toxic and pyrophoric organoantimony compound with the formula Sb(CH3)3Cl2. It is a colorless liquid with a slightly sweet odor and is highly reactive, easily forming explosive mixtures with air. TRIMETHYLANTIMONY(V) DICHLORIDE 96 is soluble in many organic solvents and is commonly used as a catalyst in organic synthesis.

13059-67-1

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13059-67-1 Usage

Uses

Used in Chemical Industry:
TRIMETHYLANTIMONY(V) DICHLORIDE 96 is used as a catalyst in organic synthesis for the production of various organic compounds and polymers. Its high reactivity and solubility in organic solvents make it a valuable component in the synthesis process.
However, due to its highly toxic and reactive nature, strict safety measures should be observed when handling and using TRIMETHYLANTIMONY(V) DICHLORIDE 96. This ensures the safety of workers and the environment while maintaining the effectiveness of the compound in its intended applications.

Check Digit Verification of cas no

The CAS Registry Mumber 13059-67-1 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,3,0,5 and 9 respectively; the second part has 2 digits, 6 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 13059-67:
(7*1)+(6*3)+(5*0)+(4*5)+(3*9)+(2*6)+(1*7)=91
91 % 10 = 1
So 13059-67-1 is a valid CAS Registry Number.
InChI:InChI=1/3CH3.2ClH.Sb/h3*1H3;2*1H;/q;;;;;+2/p-2/rC3H9Cl2Sb/c1-6(2,3,4)5/h1-3H3

13059-67-1SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name dichloro(trimethyl)-λ<sup>5</sup>-stibane

1.2 Other means of identification

Product number -
Other names Trimethylantimony dichloride

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:13059-67-1 SDS

13059-67-1Relevant academic research and scientific papers

Synthesis and spectroscopic studies of antimony pentachloride complexes with neutral oxygen, sulfur and selenium ligands

Corcoran, Sarah M.,Levason, William,Patel, Rina,Reid, Gillian

, p. 1263 - 1268 (2008/10/09)

The compounds [SbCl5(R3EY)] (R = Me or Ph; E = P or As; Y = O or S) have been prepared from SbCl5 and the appropriate ligand in CH2Cl2 or CCl4 solutions, and characterised by analysis, IR,

Synthesis, molecular structure, and isomerisation in solution of (ME 3SbS)2Me2SnCl2. Concomitant hypercoordination of tin and antimony

Beckmann, Jens,Dakternieks, Dainis,Duthie, Andrew,Foitzik, Richard C.

, p. 1508 - 1510 (2008/10/08)

The reaction of Me3SbCl2 and (Me2SnS) 3 afforded the complex (Me3SbS)2Me 2SnCl2 in high yields, whose molecular structure features both hypercoordinated tin and antimony atoms. In solution, (Me 3SbS)2Me2SnCl2 undergoes a reversible dissociation and ligand interchange reaction to give Me 3SbS, Me3SbCl2 and (Me2SnS) 3.

Syntheses of antimony(V) derivatives from trimethyl and triphenylantimony(III), dihydric phenols, and tert-butyl hydroperoxide

Dodonov, V. A.,Fedorov, A. Yu.,Usyatinsky, R. I.,Zaburdyaeva, S. N.,Gushchin, A. V.

, p. 730 - 733 (2007/10/02)

Trimethyl and triphenylantimony o-phenylene dioxides were obtained by the reaction of trimethyl- and triphenylantimony with pyrocatechol in the presence of tert-butyl hydroperoxide in 68 and 81percent yields, respectively. 7,7,7,15,15,15-hexamethyl-(and p

Alkylantimondichloride und -bromide

Ates, Mustafa,Breunig, Hans Joachim,Guelec, Sabahittin

, p. 67 - 72 (2007/10/02)

MeSbCl2 is formed by the exchange reaction of equimolar amounts of Me2SbCl with SbCl3.Alkylantimony dibromides of the type RSbBr2 with R = Me, Et, n-Pr, n-Bu are obtained by dismutation of the corresponding dialkylantimony bromides with SbBr3.Exchange as

Preparation and 121Sb M?ssbauer spectroscopy of methylchlorostibines

Stevens,Trooster,Meinema,Noltes

, p. 801 - 803 (2008/10/08)

The synthesis and 121Sb M?ssbauer spectra are reported for CH3SbCl2 and (CH3)2SbCl. The M?ssbauer spectroscopic data for the series (CH3)xSbCl3-x with x = 0-3 are discussed. The quadrupole coupling parameters of all four compounds can be explained qualitatively with a simple point charge model, assuming the bond angles between the ligands to be close to 90°. The isomer shift data indicate a decrease of s-electron density at the Sb nucleus with increase of x, which is ascribed to an increase of p character of the lone-pair electrons.

Gas-phase calorimetry of trimethyl group Va bases with boron Lewis acids

Mente, Donald C.,Mills, Jerry L.,Mitchell, Roy E.

, p. 123 - 126 (2007/11/06)

The reaction between the group Va Lewis bases trimethylphosphine, trimethylarsine, and trimethylstibine and the boron Lewis acids boron trifluoride, boron trichloride, boron tribromide, diborane, and trimethylborane has been studied using gas-phase calori

The chloramination of some substituted stibines

McKenney, Robert L.,Sisler, Harry H.

, p. 1178 - 1182 (2007/10/18)

Trimethyl-, triethyl-, tri-n-propyl-, tri-n-butyl-, and triphenylstibines react with ammonia-free chloramine or an ammonia-chloramine mixture to produce compounds of the type [R3Sb(Cl)]2NH (I). These compounds readily hydrolyze to [R3Sb-(Cl)]2O (II ). Further reactions of II are also described. Infrared and proton magnetic resonance studies were carried out on compounds of types I and II and on a variety of other antimony compounds. Qualitative assignments of infrared bands are given.

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