42496-23-1Relevant academic research and scientific papers
Alkylantimondichloride und -bromide
Ates, Mustafa,Breunig, Hans Joachim,Guelec, Sabahittin
, p. 67 - 72 (2007/10/02)
MeSbCl2 is formed by the exchange reaction of equimolar amounts of Me2SbCl with SbCl3.Alkylantimony dibromides of the type RSbBr2 with R = Me, Et, n-Pr, n-Bu are obtained by dismutation of the corresponding dialkylantimony bromides with SbBr3.Exchange as
Preparation and 121Sb M?ssbauer spectroscopy of methylchlorostibines
Stevens,Trooster,Meinema,Noltes
, p. 801 - 803 (2008/10/08)
The synthesis and 121Sb M?ssbauer spectra are reported for CH3SbCl2 and (CH3)2SbCl. The M?ssbauer spectroscopic data for the series (CH3)xSbCl3-x with x = 0-3 are discussed. The quadrupole coupling parameters of all four compounds can be explained qualitatively with a simple point charge model, assuming the bond angles between the ligands to be close to 90°. The isomer shift data indicate a decrease of s-electron density at the Sb nucleus with increase of x, which is ascribed to an increase of p character of the lone-pair electrons.
