130660-15-0

Basic information

• Product Name: 2-Hexanone, 5-methyl-5-(phenylthio)-
• CAS NO: 130660-15-0
• Molecular Formula: C13H18OS
• Molecular Weight: 222.351
• Mol File: 130660-15-0.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 2-Hexanone, 5-methyl-5-(phenylthio)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Hexanone, 5-methyl-5-(phenylthio)-(130660-15-0)
• EPA Substance Registry System: 2-Hexanone, 5-methyl-5-(phenylthio)-(130660-15-0)

Safety Data

• Hazardous Substances Data: 130660-15-0(Hazardous Substances Data)

Upstream product

• 931-59-9 benzenesulfenyl chloride 
• 108-98-5 thiophenol 
• 14252-46-1 2,2-bis(phenylthio)propane 
• 78-94-4 methyl vinyl ketone 
• 130660-14-9 (E)-5-Methyl-5-phenylsulfanyl-hex-3-en-2-one 

Downstream Products

• 17299-41-1 Isocampherphoron 
• 23438-77-9 3,6,6-trimethyl-2-cyclohexen-1-one 
• 97571-33-0 2,2-dimethyl-5-methylidenecyclohexanol 
• 161145-69-3 2,5-dimethyl-5-phenylthio-1-hexene 
• 163068-94-8 2-methyl-(3-methyl-3-phenylthiobutyl)-1,3-dioxolane 

Relevant articles and documents

The superiority of properly prepared lithium 1-N,N-dimethylaminonaphthalenide (LDMAN) over other aromatic radical-anions for the generation of organolithiums by reductive lithiation

The use of lithium 1-N,N-dimethylaminonaphthalenide (LDMAN) is found to be considerably superior in yield, ease of operation, and cost to the far more widely used lithium p,p′-di-tert-butylbiphenylide (LDBB) in reductive lithiations by aromatic radical-an

Generation, rearrangements and some synthetic uses of bishomoallyllithiums

A general preparative method for bishomoallyllithiums consists of reductive lithiation by 4,4'-di-tert-butylbiphenylide (LDBB) of bishomoallyl phenyl sulfides, which can be prepared by (1) thioacetalization of γ, δ-unsaturated ketones followed by replacin