130694-71-2

Basic information

• Product Name: Cyclohexanone,4-hydroxy-4-[(3Z)-5-hydroxy-3-methyl-3-penten-1-yn-1-yl]-3,3,5-trimethyl-,(4R,5S)-
• Synonyms: Cyclohexanone,4-hydroxy-4-(5-hydroxy-3-methyl-3-penten-1-ynyl)-3,3,5-trimethyl-, [4R-[4a,4(Z),5b]]-; Cyclohexanone,4-hydroxy-4-[(3Z)-5-hydroxy-3-methyl-3-penten-1-ynyl]-3,3,5-trimethyl-,(4R,5S)- (9CI); PBI 63
• CAS NO: 130694-71-2
• Molecular Formula: C15H22 O3
• Molecular Weight: 250.338
• Mol File: 130694-71-2.mol

Chemical Properties

• CAS DataBase Reference: Cyclohexanone,4-hydroxy-4-[(3Z)-5-hydroxy-3-methyl-3-penten-1-yn-1-yl]-3,3,5-trimethyl-,(4R,5S)-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexanone,4-hydroxy-4-[(3Z)-5-hydroxy-3-methyl-3-penten-1-yn-1-yl]-3,3,5-trimethyl-,(4R,5S)-(130694-71-2)
• EPA Substance Registry System: Cyclohexanone,4-hydroxy-4-[(3Z)-5-hydroxy-3-methyl-3-penten-1-yn-1-yl]-3,3,5-trimethyl-,(4R,5S)-(130694-71-2)

Safety Data

• Hazardous Substances Data: 130694-71-2(Hazardous Substances Data)

Upstream product

• 14203-67-9 2,2,6-trimethyl-1,4-cyclohexanedione 4-ethylene acetal 
• 6153-06-6 (E)-3-methylpent-2-en-4-yn-1-ol 
• 95307-31-6 2-trans-5-(4',4'-ethylenedioxy-1'-hydroxy-2',2',6'-trimethylcyclohexyl)-3-methylpent-2-en-4-yn-1-ol 
• 127-09-3 sodium acetate 
• 64-19-7 acetic acid 
• 95307-31-6 2-cis-5-(4',4'-ethylenedioxy-1'-hydroxy-2',2',6'-trimethylcyclohexyl)-3-methylpent-2-en-4-yn-1-ol 
• 41967-81-1 (Z)-3-Methyl-2-penten-4-ynyl tetrahydropyranyl ether 
• 130584-00-8 Acetic acid (Z)-5-[(1R,4R,6S)-4-(tert-butyl-dimethyl-silanyloxy)-1-hydroxy-2,2,6-trimethyl-cyclohexyl]-3-methyl-pent-2-en-4-ynyl ester 
• 130584-04-2 (+)-1(Z)-(1R,4R,6S)-4-tert-butyldimethylsiloxy-1-(5-hydroxy-3-methylpent-3-en-1-ynyl)-2,2,6-trimethylcyclohexanol 
• 130583-99-2 (+)-1(Z)-(1R,4R,6S)-1-(5-acetoxy-3-methylpent-3-en-1-ynyl)-2,2,6-trimethylcyclohexan-1,4-diol 
• 130694-69-8 (+)-(4R,6S)-4-tert-butyldimethylsiloxy-2,2,6-trimethylcyclohexanone 
• 60046-49-3 (6R)-levodione 
• 60686-81-9 (+)-(4R,6S)-4-hydroxy-2,2,6-trimethylcyclohexanone 
• 20548-02-1 (4R,6R)-4-hydroxy-2,2,6-trimethylcyclohexan-1-one 

Downstream Products

• 137349-54-3 (E)-3-Methyl-5-(2,6,6-trimethyl-4-oxo-cyclohex-1-enyl)-pent-2-en-4-ynoic acid methyl ester 
• 137349-52-1 (E)-3-Methyl-5-(2,6,6-trimethyl-4-oxo-cyclohex-2-enylidene)-penta-2,4-dienoic acid methyl ester 
• 130583-85-6 (E)-5-((1S,6R)-1-Hydroxy-2,2,6-trimethyl-4-oxo-cyclohexyl)-3-methyl-pent-2-en-4-ynoic acid methyl ester 
• 95307-34-9 3,5,5-Trimethyl-4-[(3E,5E,7E,9E,11E,13E,15E,17E)-3,7,12,16-tetramethyl-18-(2,6,6-trimethyl-cyclohex-2-enyl)-octadeca-3,5,7,9,11,13,15,17-octaen-1-ynyl]-cyclohex-3-enol 
• 70905-70-3 2-trans-5-(4'-acetoxy-1'-hydroxy-2',2',6'-trimethylcyclohexyl)-1-acetoxy-3-methylpent-2-en-4-yne 
• 70905-70-3 Acetic acid (1R,4S,5R)-4-((Z)-5-acetoxy-3-methyl-pent-3-en-1-ynyl)-4-hydroxy-3,3,5-trimethyl-cyclohexyl ester 
• 95343-64-9 2-trans-1-acetoxy-5-(4'-acetoxy-2',2',6'-trimethylcyclohex-1'-enyl)-3-methylpent-2-en-4-yne 
• 95343-65-0 2-trans-5-(4'-hydroxy-2',2',6'-trimethylclohex-1'-enyl)-3-methylpent-2-en-4-yn-1-yltriphenylphosphonium bromide 
• 95307-44-1 [(E)-5-(4-Acetoxy-2,6,6-trimethyl-cyclohex-1-enyl)-3-methyl-pent-2-en-4-ynyl]-triphenyl-phosphonium; bromide 
• 95307-42-9 2-trans-5-(4'-hydroxy-2',2',6'-trimethylclohex-1'-enyl)-3-methylpent-2-en-4-yn-1-ol 
• 26533-78-8 9-trans-3-hydroxy-7,8-didehydro-12'-apo-β-caroten-12'-al 
• 137349-51-0 (Z)-3-Methyl-5-(2,6,6-trimethyl-4-oxo-cyclohex-1-enyl)-pent-2-en-4-ynoic acid methyl ester 
• 137349-52-1 (Z)-3-Methyl-5-(2,6,6-trimethyl-4-oxo-cyclohex-2-enylidene)-penta-2,4-dienoic acid methyl ester 
• 130583-85-6 (Z)-5-((1S,6R)-1-Hydroxy-2,2,6-trimethyl-4-oxo-cyclohexyl)-3-methyl-pent-2-en-4-ynoic acid methyl ester 

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The abscisic acid analogs (-)-(4R,5R)-, (+)-(4S,5S)-, and (-)-(4S,5R)-4(1E,3Z)-4-(4-carboxy-3-methyl-1,3-butadienyl)-4-hydroxy-3,3,5-trimethylcyclohexanones (dihydroabscisic acids), and (-)-(4S,5R)-, (+)-(4R,5S)-, and (-)-(4R,5R)-4(Z)-4-hydroxy-4-(5-hydroxy-3-methylpent-3-en-1-ynyl)-3,3,5-trimethylcyclohexanones were synthesized from a common precursor, (-)-(6R)-2,2,6-trimethylcyclohexan-1,4-dione, which was readily prepared by the fermentation of oxoisophorone with bakers' yeast.

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