13075-05-3Relevant academic research and scientific papers
Isostructurality, polymorphism and mechanical properties of some hexahalogenated benzenes: The nature of halogen...halogen interactions
Reddy, C. Malla,Kirchner, Michael T.,Gundakaram, Ravi C.,Padmanabhan, K. Anantha,Desiraju, Gautam R.
, p. 2222 - 2234 (2008/01/27)
The nature of intermolecular interactions between halogen atoms, X...X (X = Cl, Br, I), continues to be of topical interest because these interactions may be used as design elements in crystal engineering. Hexahalogenated benzenes (C6Cl6-n
PERBROMINATION OF BENZENE AND SOME OF ITS DERIVATIVES
Golounin, A. V.,Shukhta, T. K.,Kirienko, E. K.,Petrova, M. P.,Esavkin, E. V.
, p. 1167 - 1169 (2007/10/02)
Perbrominated compounds - pentabromophenol, hexabromobenzene, pentabromotoluene, polychlorobromobenzenes, and decabromodiphenyl ether - have been obtained.Substitution bromination has been discovered in treating diphenyl sulfoxide, diphenyl sulfide, diphenylmethane, diphenyl oxide, and benzophenone with excess bromine in the presence of AlBr3.A series of ethers and esters of pentabromophenol have been obtained; their hydrolysis has been carried out.A negative influence of ferric halides has been discovered in exhaustive bromination of aromatic compounds.
POLYBROMINATED AROMATIC COMPOUNDS VI. EXHAUSTIVE BROMINATION IN THE RING OF DEACTIVATED AROMATIC COMPOUNDS
Shishkin, V.N.,Bolusheva, I.Yu.,Lapin, K.K.,Tanaseichuk, B.S.
, p. 1303 - 1308 (2007/10/02)
A convenient method is developed for the synthesis of perbrominated aromatic compounds containing electronegative groups (NO2, CN, COOH) by exhaustive bromination of the starting compounds with bromine in concentrated sulfuric acid in oleum in the presence of mecuric oxide at 35-60 deg C.
BROMINATION OF SOME AROMATIC COMPOUNDS BY MEANS OF BROMINE IN TETRACHLOROETHANE MEDIUM.
Hashem
, p. 59 - 61 (2007/10/05)
Bromination of some aromatic compounds is carried out using bromine in tetrachloroethane medium in the presence of iodine as a halogen carrier. The compounds investigated here are classified into: compounds which yield pentabromophenol, compounds which yield other polybromoderivatives, and those which do not react with the brominating agent.
