1825-26-9Relevant academic research and scientific papers
Inverse kinetic solvent isotope effect in TIO2 photocatalytic dehalogenation of non-adsorbable aromatic halides: A proton-induced pathway
Chang, Wei,Sun, Chunyan,Pang, Xibin,Sheng, Hua,Li, Yue,Ji, Hongwei,Song, Wenjing,Chen, Chuncheng,Wanhong, Ma.,Zhao, Jincai
, p. 2052 - 2056 (2015)
An efficient redox reaction between organic substrates in solution and photoinduced h+vb/e -cb on the surface of photocatalysts requires the substrates or solvent to be adsorbed onto the surface, and is conseque
Polybromoaromatic compounds: VII. Reactions of pentabromofluorobenzene and hexabromobenzene with some nucleophilic reagents
Shishkin,Lapin,Olenina,Butin
, p. 1032 - 1038 (2007/10/03)
Reactions of pentabromofluorobenzene with sodium alkoxides RONa (R = CH3, iso-C3H7, C4H9, tert-C4H9, C5H11, C6H13) in pyridine yield m
Regioselectivity of methoxydebromination of substituted pentabromobenzenes C6Br5X in pyridine
Shishkin, V. N.,Lapin, K. K.,Shabarina, S. A.,Butin, K. P.
, p. 1715 - 1719 (2007/10/03)
The kinetics and regioselectivity of methoxydebromination of some substituted pentabromobenzenes C6Br5X (X = NO2, CN, NH2, MeNH, and MeO) were studied in pyridine at 115 deg C.The partial rate factors (kf) were calculated for different position
POLYBROMINATED AROMATIC COMPOUNDS. IV. METHOXYDEBROMINATION REACTIONS OF POLYBROMOBENZENES IN PYRIDINE
Shishkin, V. N.,Lapin, K. K.,Tanaseichuk, B. S.,Butin, K. P.
, p. 516 - 522 (2007/10/02)
The rates were measured and the orientation was studied for the methoxydebromination of all polybromobenzenes C6HnBr6-n (n = 0-3) in pyridine at 115 deg C.From comparison of the partial rates of substitution of the bromine atom at various positions of the benzene ring it was found that the activating effect of the bromine atom in relation to the point of nucleophilic attack changes in the order o-Br > m-Br > p-Br, and the directing selectivity of the bromine is low (compared with fluorine in the methoxydefluorination of polyfluorobenzenes) and increases with decrease in the number of bromine atoms in the aromatic ring of the substrate.
POLYBROMINATED AROMATIC COMPOUNDS. II. REACTIONS OF PENTABROMOCHLOROBENZENE WITH SODIUM ALKOXIDES IN PYRIDINE
Shishkin, V. N.,Tachaseichuk, B. S.,Balashov, A. V.,Butin, K. P.
, p. 1302 - 1308 (2007/10/02)
The reaction of pentabromochlorobenzene with sodium methoxide and butoxide in pyridine was investigated.The main reaction products are the products from substitution of the bromine and chlorine atoms by the alkoxy group, and their distribution corresponds
