130800-03-2

Upstream product

• 36076-26-3 diethyl 2,2'-(1,4-phenylene)diacetate 
• 7325-46-4 1,4-phenylenediacetic acid 
• 5140-03-4 2-[4-(2-hydroxyethyl)phenyl]ethan-1-ol 
• 130800-02-1 2,2'-(1,4-phenylene)diethyl dimesylate 
• 4542-72-7 1,4-bis-(2-bromoethyl)benzene 

Downstream Products

• 53-70-3 dibenzo[a,h]anthracene 
• 888721-99-1 4,4'-(1,4-phenylene)bis[2-(dimethylsulfanylidene)butanal] 
• 888721-96-8 4,4'-(1,4-phenylene)bis[2-(methylthio)butanal] 
• 130800-14-5 C₂₂H₃₀O₂ 
• 130800-13-4 C₂₂H₃₀O₂ 

Relevant academic research and scientific papers

Highly regioselective transformation of out/out-equatorial bis(formylmethano)[60]fullerenes: Construction of dissymmetric [60]fullerene-centered triads

Three kinds of out/out-equatorial bis(formylmethano)[60]fullerenes (1b-d) were obtained by the tether-directed bifunctionalization of [60]fullerene with bis(α-formylsulfonium ylide)s. The condensation of aromatic amines with 1b-d proceeded with an unexpec

Regio- and diastereo-controlled synthesis of bis(formylmethano)[60]fullerenes and their application to the formation of [60]fullerene pearl-necklace polyimines

The tether-directed method was firstly applied to the biscyclopropanation of [60]fullerene via the addition-elimination reaction of bis(sulfonium ylide)s to give bis(formylmethano)[60]fullerenes with satisfactory regio- and stereoselectivity. The equatori

A New General Synthesis of Polycyclic Aromatic Compounds Based on Enamine Chemistry

Alkylation of enamines and enamine salts by benzylic and (β-haloethyl)aryl halides, respectively, followed by acidic cyclodehydration and dehydrogenation provides an efficient synthetic approach to a wide range of polycyclic aromatic compounds of diverse structural types.Specific polycyclic hydrocarbons synthesized by this route include benzo- and benzofluorene, 7H-dibenzo-, 13H-dibenzo-, and 13H-dibenzofluorene, 15H-tribenzofluorene, dibenzochrysene, benzopentaphene, indenofluorene, fluorenofluorene, octahydrodibenzanthracene, dibenzanthracene, octahydrodibenzanthracene, dibenzanthracene, picene, benzopicene, 1H-benzaceanthrylene, and 4H-cyclopentachrysene.This method with appropriate modifications appears to be potentially broader in scope than established traditional methods of polycyclic hydrocarbon synthesis.