13083-96-0 Usage
Uses
Used in Chemical Reactions:
1,6-Bis(Trimethylsilyl)Hexane is used as a silylating agent for protecting reactive hydroxyl groups in chemical reactions. This protection allows chemists to temporarily modify the reactivity of these functional groups, facilitating the synthesis of complex organic compounds.
Used in High-Performance Liquid Chromatography (HPLC):
In the HPLC industry, 1,6-Bis(Trimethylsilyl)Hexane is used as a stationary phase or a component of the mobile phase to separate and analyze various compounds. Its unique properties enable the efficient separation of complex mixtures, making it a valuable tool in analytical chemistry.
Used in Gas Chromatography (GC):
1,6-Bis(Trimethylsilyl)Hexane is utilized as a stationary phase in gas chromatography, where it helps in the separation and identification of volatile compounds. Its ability to interact with a wide range of analytes makes it a versatile choice for GC applications.
Used in Thin-Layer Chromatography (TLC):
In the field of thin-layer chromatography, 1,6-Bis(Trimethylsilyl)Hexane is employed as a mobile phase component to separate and identify compounds on a solid support. Its unique properties contribute to the efficient separation of various compounds, making it a valuable tool in analytical chemistry.
Used in Organic Syntheses:
1,6-Bis(Trimethylsilyl)Hexane is used as a silylating agent in organic syntheses for temporarily modifying the reactivity of certain functional groups. This modification allows chemists to perform reactions that would otherwise be challenging or impossible, facilitating the synthesis of complex organic compounds.
Check Digit Verification of cas no
The CAS Registry Mumber 13083-96-0 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,3,0,8 and 3 respectively; the second part has 2 digits, 9 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 13083-96:
(7*1)+(6*3)+(5*0)+(4*8)+(3*3)+(2*9)+(1*6)=90
90 % 10 = 0
So 13083-96-0 is a valid CAS Registry Number.
13083-96-0Relevant academic research and scientific papers
Absolute Rate Constants for Some Intermolecular and Intramolecular Reactions of α-, β-, and γ-Silicon-Substituted Radicals
Wilt, James W.,Lusztyk, J.,Peeran, Mehoob,Ingold, K. U.
, p. 281 - 287 (2007/10/02)
Rate constants for hydrogen atom abstraction from n-Bu3GeH (kGeH) by Me3SiCH2. (1.), Me3SiCH2CH2. (2.), and Me3SiCH2CH2CH2. (3.) and from n-Bu3SnH (kSnH) by 1. and 3. have been determined at ambient temperatures.The order of decreasing radical reactivity is 1. > n-alkyl > 3. > 2..However, for bromine abstraction from the parent bromides by n-Bu3Sn. and n-Bu3Ge., the order of decreasing reactivity is 1-Br > 2-Br > 3-Br ca. n-alkyl bromide.The Arrhenius equations for reaction of 1. and 3. with n-Bu3SnH were also determined: log (kSnH(1.)/(M-1 s-1)) = (10.2 +/- 0.5) - (3.90 +/- 0.62)/Θ and log (kSnH(3.)/(M-1 s-1)) = (8.4 +/- 0.7) - (2.81 +/- 0.95)/Θ, where Θ = 2.3RT kcal/mol.These kinetic data are discussed in relation to previously measured rate constant ratios, kc5+6/kSnH and kexo5/kendo6, where kc5+6 corresponds to the cyclization of α-, β-, and γ-dimethylsilyl-substituted 5-hexenyl radicals to form 5-membered (kexo5) and 6-membered (kendo6) silacycloalkylmethyl radicals.
