130896-44-5Relevant academic research and scientific papers
1,3-DIPOLAR CYCLOADDITION OF DI-1-MENTHYL BENZYLIDENEMALONATE TO (Z)-N,α-DIPHENYLNITRONE: EXPLANATION FOR DIASTEREOSELECTIVITY
Katagiri, Nobuya,Watanabe, Nobuhisa,Sakaki, Jun-ichi,Kawai, Takatoshi,Kaneko, Chikara
, p. 4633 - 4636 (1990)
1,3-Dipolar cycloaddition of di-1-menthyl benzylidenemalonate to (Z)-N,α-diphenylnitrone proceeds by Si-face preference to give the endo-adduct as the major product among all four possible adducts.An explanation for this diastereofacial selectivity (Si-fa
