1,3-DIPOLAR CYCLOADDITION OF DI-1-MENTHYL BENZYLIDENEMALONATE TO (Z)-N,α-DIPHENYLNITRONE: EXPLANATION FOR DIASTEREOSELECTIVITY

DOI: 10.1016/S0040-4039(00)97694-9

Source and publish data:

Tetrahedron Letters p. 4633 - 4636 (1990)

Update date:2022-09-26

Topics:

Authors:

Katagiri, Nobuya

Watanabe, Nobuhisa

Sakaki, Jun-ichi

Kawai, Takatoshi

Kaneko, Chikara

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Article abstract of DOI:10.1016/S0040-4039(00)97694-9

1,3-Dipolar cycloaddition of di-1-menthyl benzylidenemalonate to (Z)-N,α-diphenylnitrone proceeds by Si-face preference to give the endo-adduct as the major product among all four possible adducts.An explanation for this diastereofacial selectivity (Si-fa

Full text of DOI:10.1016/S0040-4039(00)97694-9

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