Tetrahedron Letters p. 4633 - 4636 (1990)
Update date:2022-09-26
Topics:
Katagiri, Nobuya
Watanabe, Nobuhisa
Sakaki, Jun-ichi
Kawai, Takatoshi
Kaneko, Chikara
1,3-Dipolar cycloaddition of di-1-menthyl benzylidenemalonate to (Z)-N,α-diphenylnitrone proceeds by Si-face preference to give the endo-adduct as the major product among all four possible adducts.An explanation for this diastereofacial selectivity (Si-fa
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