131087-27-9

Upstream product

• 100-39-0 benzyl bromide 
• 131087-26-8 (2S,3S,4R)-3-Benzyloxy-1,2-cyclopentylidenedioxy-4-hydroxyheptane 
• 23786-93-8 1,1-diethoxy-cyclopentane 
• 131087-25-7 (2S,3S,4R)-3-Benzyloxy-1,2,4-trihydroxyheptane 
• 89755-50-0 1,2-O-Isopropylidene-3-O-benzyl-5-deoxy-5-C-ethyl-α-D-xylofuranose 
• 89755-55-5 (3aR,5R,6S,6aR)-6-Benzyloxy-2,2-dimethyl-5-((E)-propenyl)-tetrahydro-furo[2,3-d][1,3]dioxole 
• 18685-18-2 3-O-benzyl-1,2-5,6-O-diisopropylidene-α-D-glucofuranose 
• 23558-05-6 3-O-benzyl-1,2-O-isopropylidene-1,5-D-xylo-dialdofuranose 
• 131087-25-7 (2S,3R,4R)-3-Benzyloxy-1,2,4-trihydroxyheptane 
• 146072-00-6 (3aR,5R,6aS)-2,2-Dimethyl-5-propyl-dihydro-furo[2,3-d][1,3]dioxol-6-one 
• 146072-02-8 3-O-Benzyl-5-deoxy-5-C-ethyl-1,2-O-isopropylidene-α-D-ribofuranose 
• 89755-49-7 5-Deoxy-5-C-ethyl-1,2-O-isopropylidene-α-D-xylofuranose 
• 146072-01-7 5-Deoxy-5-C-ethyl-1,2-O-isopropylidene-α-D-ribofuranose 
• 22331-21-1 1,2:5,6-di-O-isopropylidene-3-O-benzyl-α-D-allofuranose 

Downstream Products

• 131087-28-0 (2S,3S,4R)-3,4-Dibenzyloxy-1,2-dihydroxyheptane 
• 131087-30-4 6-((1S,2R)-1,2-Bis-benzyloxy-pentyl)-4-hydroxy-5,6-dihydro-pyran-2-one 
• 131087-31-5 (6RS,1'S,2'R)-6-(1',2'-Dibenzyloxypentyl)-5,6-dihydro-4-methoxypyrane-2-one 
• 41164-59-4 (6R,1'S,2'R)-6-(1',2'-Dihydroxypentyl)-5,6-dihydro-4-methoxypyrane-2-one 
• 41164-59-4 hydroxypestalotin 
• 131087-28-0 (2S,3S,4R)-3,4-Bis-benzyloxy-heptane-1,2-diol 
• 146072-04-0 (2R,3R)-2,3-Bis-benzyloxy-hexanal 
• 131087-30-4 6-((1R,2R)-1,2-Bis-benzyloxy-pentyl)-4-hydroxy-5,6-dihydro-pyran-2-one 
• 146143-46-6 (6R,1'R,2'R)-6-(1',2'-Dibenzyloxypentyl)-5,6-dihydro-4-methoxypyran-2-one 
• 146143-45-5 (6S,1'R,2'R)-6-(1',2'-Dibenzyloxypentyl)-5,6-dihydro-4-methoxypyran-2-one 
• 131087-29-1 (2S,3R)-2,3-Dibenzyloxyhexanal 

Relevant academic research and scientific papers

Stereoselective Synthesis of Unnatural Stereoisomers of LL-P880β and LL-P880γ, Pestatolin Analogues from Penicillium sp.

A synthesis of unnatural stereoisomers of LL-P880β and (2) and subsequent transformation of 2 into LL-P880γ (3) were achieved by starting from diacetoneglucose (4).A chiral building block, 5-deoxy-α-D-ribofuranose derivative 9, was derived from 4 by two s

Total Synthesis of (6S,1'S,2'R)-6-(1',2'-Dihydroxypentyl)-4-methoxy-5,6-dihydropyrane-2-one (LL-P880β) and Its C6-Epimer, a Fungal Metabolite from Penicillium sp.

A fungal metabolite, (6S,1'S,2'R)-6-(1',2'-dihydroxypentyl)-4-methoxy-5,6-dihydropyrane-2-one (LL-P880β, I), and its C6-epimer (II) were synthesized by the chiron approach.The key intermediate, (2S,3R)-2,3-dihydroxyhexanal derivative (3), was p