1311164-69-8

Basic information

• Product Name: carbonylchlorohydrido[bis(2-diisopropyl-phosphinoethyl)amino]ruthenium(II)
• CAS NO: 1311164-69-8
• Molecular Weight: 470.965
• Mol File: 1311164-69-8.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: carbonylchlorohydrido[bis(2-diisopropyl-phosphinoethyl)amino]ruthenium(II)(CAS DataBase Reference)
• NIST Chemistry Reference: carbonylchlorohydrido[bis(2-diisopropyl-phosphinoethyl)amino]ruthenium(II)(1311164-69-8)
• EPA Substance Registry System: carbonylchlorohydrido[bis(2-diisopropyl-phosphinoethyl)amino]ruthenium(II)(1311164-69-8)

Safety Data

• Hazardous Substances Data: 1311164-69-8(Hazardous Substances Data)

Upstream product

• 124-38-9 carbon dioxide 
• 1333-74-0 hydrogen 
• 20491-53-6 di-isopropylphosphine 
• 40244-90-4 Chlorodiisopropylphosphane 
• 157072-60-1 (carbonyl)(chloro)(hydrido)tris(triphenylphosphine)ruthenium(II) 
• 131890-26-1 bis[2-(di-iso-propylphosphino)ethyl]amine 

Relevant articles and documents

Dynamic Kinetic Resolution of Alcohols by Enantioselective Silylation Enabled by Two Orthogonal Transition-Metal Catalysts

A nonenzymatic dynamic kinetic resolution of acyclic and cyclic benzylic alcohols is reported. The approach merges rapid transition-metal-catalyzed alcohol racemization and enantioselective Cu-H-catalyzed dehydrogenative Si-O coupling of alcohols and hydrosilanes. The catalytic processes are orthogonal, and the racemization catalyst does not promote any background reactions such as the racemization of the silyl ether and its unselective formation. Often-used ruthenium half-sandwich complexes are not suitable but a bifunctional ruthenium pincer complex perfectly fulfills this purpose. By this, enantioselective silylation of racemic alcohol mixtures is achieved in high yields and with good levels of enantioselection.

N,N-BIS(2-DIALKYLPHOSPHINOETHYL)AMINE-BORANE COMPLEX AND PRODUCTION METHOD THEREFOR, AND METHOD FOR PRODUCING RUTHENIUM COMPLEX CONTAINING N,N-BIS(2-DIALKYLPHOSPHINOETHYL)AMINE AS LIGAND

The purpose of the present invention is to provide an N,N-bis(2-dialkylphosphinoethyl)amine-borane complex which is a ruthenium complex that exhibits excellent catalytic activity in a hydrogenation reaction, etc., and a production method therefor, and a method for efficiently producing a ruthenium complex containing N,N-bis(2-dialkylphosphinoethyl)amine as a ligand. The present invention is capable of efficiently producing an amine-borane complex (3) by reacting an oxazolidinone compound (1) with a dialkylphosphine-borane compound (2) in the presence of a base. The present invention is also capable of efficiently producing a ruthenium complex (5) by reacting the amine-borane complex (3) with a ruthenium compound (4) in the presence of an amine. (In the formula, a solid line, a dashed line, B, C, H, L1-L3, LG, n, N, O, P, Ru, X, and R1-R10 are as defined in the description.)

METHOD FOR ALKYLATION OF AMINES

The present invention provides a simple, efficient, and industrially advantageous method for the alkylation of amines. The present invention relates to a production method for N-alkylamines whereby an amine is reacted with an alcohol in the presence of a ruthenium complex represented by general formula (1): RuXY(CO)(L) (wherein X and Y can be the same or different and represent a monovalent anionic ligand, and L represents a tridentate aminodiphosphine ligand).